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Literature DB >> 29076224

Quantum Monte Carlo Simulations and High-Field Magnetization Studies of Antiferromagnetic Interactions in a Giant Hetero-Spin Ring.

Lei Qin¹, Jared Singleton², Wei-Peng Chen¹, Hiroyuki Nojiri³, Larry Engelhardt², Richard E P Winpenny⁴, Yan-Zhen Zheng¹.

Abstract

Chromium lanthanide heterometallic wheel complexes {Cr8 Ln8 } (Ln=Gd, Dy and Y) with alternating metal centres are presented. Quantum Monte Carlo simulations reveal antiferromagnetic exchange-coupling constants with an average of 2.1 K within the {Cr8 Gd8 } wheel, which leads to a large ground spin state (ST =16) that is confirmed by magnetization studies up to 20 Tesla. The {Cr8 Dy8 } wheel is a single-molecule magnet.

Entities: Chemical

Keywords: chromium; cyclic coordination clusters; exchange coupling; lanthanides; single-molecule magnets

Year: 2017 PMID： 29076224 DOI： 10.1002/anie.201709650

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

4 in total

1. Quantum Monte Carlo simulations of a giant {Ni₂₁Gd₂₀} cage with a S = 91 spin ground state.

Authors: Wei-Peng Chen; Jared Singleton; Lei Qin; Agustín Camón; Larry Engelhardt; Fernando Luis; Richard E P Winpenny; Yan-Zhen Zheng
Journal: Nat Commun Date: 2018-05-29 Impact factor: 14.919

2. A new family of decanuclear Ln₇Cr₃ clusters exhibiting a magnetocaloric effect.

Authors: Jia-Jia Yin; Tian-Qi Lu; Cheng Chen; Hai-Yan Shi; Gui-Lin Zhuang; Jun Zheng; Xiaolong Fang; Xiu-Ying Zheng
Journal: RSC Adv Date: 2021-05-12 Impact factor: 4.036

3. Synthesis, crystal structures and magnetic properties of two heterometallic {Ln₈Cr₄} (Ln = Gd³⁺ and Tb³⁺) complexes with one-dimensional wave chain structure.

Authors: Ye-Min Han; Ning-Fang Li; Yan-Zhao Yu; Jia-Peng Cao; Mu-Xiu Yang; Ya-Lin Hong; Run-Kun Kang; Peng Yuan; Yan Xu
Journal: RSC Adv Date: 2020-03-20 Impact factor: 4.036

4. Incorporating polyoxometalates and organic ligands to pursue 3d-4f heterometallic clusters: a series of {Cr₄Ln₄} clusters stabilized by phthalic acid and [SiW₁₂O₄₀]⁴.

Authors: Ya-Nan Gu; Dan Zhao; Hao Yu; Rui Ge; Zhong Li; Chong-Bian Tian; Xin-Xiong Li; Yan-Qiong Sun; Shou-Tian Zheng
Journal: RSC Adv Date: 2019-05-01 Impact factor: 3.361

4 in total

Quantum Monte Carlo Simulations and High-Field Magnetization Studies of Antiferromagnetic Interactions in a Giant Hetero-Spin Ring.

1. Quantum Monte Carlo simulations of a giant {Ni21Gd20} cage with a S = 91 spin ground state.

2. A new family of decanuclear Ln7Cr3 clusters exhibiting a magnetocaloric effect.

3. Synthesis, crystal structures and magnetic properties of two heterometallic {Ln8Cr4} (Ln = Gd3+ and Tb3+) complexes with one-dimensional wave chain structure.

4. Incorporating polyoxometalates and organic ligands to pursue 3d-4f heterometallic clusters: a series of {Cr4Ln4} clusters stabilized by phthalic acid and [SiW12O40]4.

1. Quantum Monte Carlo simulations of a giant {Ni₂₁Gd₂₀} cage with a S = 91 spin ground state.

2. A new family of decanuclear Ln₇Cr₃ clusters exhibiting a magnetocaloric effect.

3. Synthesis, crystal structures and magnetic properties of two heterometallic {Ln₈Cr₄} (Ln = Gd³⁺ and Tb³⁺) complexes with one-dimensional wave chain structure.

4. Incorporating polyoxometalates and organic ligands to pursue 3d-4f heterometallic clusters: a series of {Cr₄Ln₄} clusters stabilized by phthalic acid and [SiW₁₂O₄₀]⁴.