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Literature DB >> 29067362

Palladium-catalyzed C-H activation/C-C cross-coupling reactions via electrochemistry.

Cong Ma¹, Chuan-Qi Zhao, Yi-Qian Li, Li-Pu Zhang, Xue-Tao Xu, Kun Zhang, Tian-Sheng Mei.

Abstract

Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electrochemical strategy to achieve methylation and acylation.

Entities: Chemical

Year: 2017 PMID： 29067362 DOI： 10.1039/c7cc07429h

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations.

Authors: Long Yang; Ralf Steinbock; Alexej Scheremetjew; Rositha Kuniyil; Lars H Finger; Antonis M Messinis; Lutz Ackermann
Journal: Angew Chem Int Ed Engl Date: 2020-05-12 Impact factor: 15.336

2. Nickela-electrocatalyzed C-H Alkoxylation with Secondary Alcohols: Oxidation-Induced Reductive Elimination at Nickel(III).

Authors: Shou-Kun Zhang; Julia Struwe; Lianrui Hu; Lutz Ackermann
Journal: Angew Chem Int Ed Engl Date: 2020-01-16 Impact factor: 15.336

3. Copper mediated one-pot synthesis of quinazolinones and exploration of piperazine linked quinazoline derivatives as anti-mycobacterial agents.

Authors: Satyaveni Malasala; Jitendra Gour; Md Naiyaz Ahmad; Srikanth Gatadi; Manjulika Shukla; Grace Kaul; Arunava Dasgupta; Y V Madhavi; Sidharth Chopra; Srinivas Nanduri
Journal: RSC Adv Date: 2020-12-08 Impact factor: 4.036

Palladium-catalyzed C-H activation/C-C cross-coupling reactions via electrochemistry.

1. Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations.

2. Nickela-electrocatalyzed C-H Alkoxylation with Secondary Alcohols: Oxidation-Induced Reductive Elimination at Nickel(III).

3. Copper mediated one-pot synthesis of quinazolinones and exploration of piperazine linked quinazoline derivatives as anti-mycobacterial agents.

4. Rhoda-Electrocatalyzed C-H Methylation and Paired Electrocatalyzed C-H Ethylation and Propylation.

5. Non-directed Pd-catalysed electrooxidative olefination of arenes.

6. Carboxylate breaks the arene C-H bond via a hydrogen-atom-transfer mechanism in electrochemical cobalt catalysis.