| Literature DB >> 29048719 |
Siyuan Liu1,2, Marc-André Légaré1,2, Dominic Auerhammer1,2, Alexander Hofmann1,2, Holger Braunschweig1,2.
Abstract
The base-stabilized borylene [Cp(OC)2 Mn=BtBu(IMe)] readily reacts with elemental chalcogens in an insertion reaction that yields borachalcone complexes [Cp(OC)2 Mn-E=BtBu(IMe)] (E=S, Se, Te). The tellurium example features the first double bond between boron and tellurium, making Te the heaviest main-group element to make multiple bonds with boron. This unprecedented interaction has been fully investigated both experimentally and computationally.Entities:
Keywords: boron; manganese; multiple bonds; subvalent compounds; tellurium
Year: 2017 PMID： 29048719 DOI： 10.1002/anie.201708729
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336