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Literature DB >> 29046059

Bis(dipyrrinato)zinc(II) Complex Chiroptical Wires: Exfoliation into Single Strands and Intensification of Circularly Polarized Luminescence.

Risa Aoki¹, Ryojun Toyoda¹, Julius F Kögel², Ryota Sakamoto^1,3, Jatish Kumar⁴, Yasutaka Kitagawa⁵, Koji Harano¹, Tsuyoshi Kawai⁴, Hiroshi Nishihara¹.

Abstract

One-dimensional (1D) coordination polymers (CPs) experiences limitations in exfoliation into individual strands, which hamper their utility as functional 1D nanomaterials. Here we synthesize chiral 1D-CPs that feature the bis(dipyrrinato)zinc(II) complex motif. They can be exfoliated into single strands upon sonication in organic media, retaining lengths of up to 3.19 μm (ca. 2600 monomer units). Their chiroptical structure allows the exfoliated wires to show circularly polarized luminescence at an intensity 5.9 times that of reference monomer complexes.

Entities: Chemical

Year: 2017 PMID： 29046059 DOI： 10.1021/jacs.7b07077

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

7 in total

1. Circularly polarised luminescence in an RNA-based homochiral, self-repairing, coordination polymer hydrogel.

Authors: Osama El-Zubir; Pablo Rojas Martinez; Gema Dura; Lamia L G Al-Mahamad; Thomas Pope; Thomas J Penfold; Lewis E Mackenzie; Robert Pal; Jackie Mosely; Fabio Cucinotta; Liam F McGarry; Benjamin R Horrocks; Andrew Houlton
Journal: J Mater Chem C Mater Date: 2022-04-20 Impact factor: 8.067

7. Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning.

Authors: Min Zeng; Ang Ren; Wubin Wu; Yongsheng Zhao; Chuanlang Zhan; Jiannian Yao
Journal: Chem Sci Date: 2020-08-04 Impact factor: 9.825

7 in total

Bis(dipyrrinato)zinc(II) Complex Chiroptical Wires: Exfoliation into Single Strands and Intensification of Circularly Polarized Luminescence.

1. Circularly polarised luminescence in an RNA-based homochiral, self-repairing, coordination polymer hydrogel.

2. CPL on/off control of an assembled system by water soluble macrocyclic chiral sources with planar chirality.

3. Unraveling Mechanisms of Chiral Induction in Double-Helical Metallopolymers.

Review 4. Functional Supramolecular Architectures of Dipyrrin Complexes.

5. Photon-upconverting chiral liquid crystal: significantly amplified upconverted circularly polarized luminescence.

6. Catalytically active coordination polymer with a tiny Zn₂Se₂ ring bridged by bis-selone.

7. Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning.

Bis(dipyrrinato)zinc(II) Complex Chiroptical Wires: Exfoliation into Single Strands and Intensification of Circularly Polarized Luminescence.

1. Circularly polarised luminescence in an RNA-based homochiral, self-repairing, coordination polymer hydrogel.

2. CPL on/off control of an assembled system by water soluble macrocyclic chiral sources with planar chirality.

3. Unraveling Mechanisms of Chiral Induction in Double-Helical Metallopolymers.

Review 4. Functional Supramolecular Architectures of Dipyrrin Complexes.

5. Photon-upconverting chiral liquid crystal: significantly amplified upconverted circularly polarized luminescence.

6. Catalytically active coordination polymer with a tiny Zn2Se2 ring bridged by bis-selone.

7. Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning.

6. Catalytically active coordination polymer with a tiny Zn₂Se₂ ring bridged by bis-selone.