Literature DB >> 29028345

Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si-H Bonds.

Hoda Keipour1, Thierry Ollevier1.   

Abstract

An efficient iron-catalyzed carbene insertion reaction of α-diazo carbonyl compounds into the Si-H bond was developed. A wide range of α-silylesters was obtained in high yields (up to 99%) from α-diazoesters using a simple iron(II) salt as catalyst.

Entities:  

Year:  2017        PMID： 29028345     DOI： 10.1021/acs.orglett.7b02488

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Chemoselective Cyclopropanation over Carbene Y-H Insertion Catalyzed by an Engineered Carbene Transferase.

Authors:  Eric J Moore; Viktoria Steck; Priyanka Bajaj; Rudi Fasan
Journal:  J Org Chem       Date:  2018-07-06       Impact factor: 4.354

2.  FeII-catalysed insertion reaction of α-diazocarbonyls into X-H bonds (X = Si, S, N, and O) in dimethyl carbonate as a suitable solvent alternative.

Authors:  Nour Tanbouza; Hoda Keipour; Thierry Ollevier
Journal:  RSC Adv       Date:  2019-10-02       Impact factor: 4.036

3.  Rh(III)-Catalyzed C-H Activation/Intramolecular Cyclization: Access to N-Acyl-2,3-dihydro-1H-carbazol-4(9H)-ones from Cyclic 2-Diazo-1,3-diketones and N-Arylamides.

Authors:  Youpeng Zuo; Xinwei He; Yi Ning; Yuhao Wu; Yongjia Shang
Journal:  ACS Omega       Date:  2017-11-30

4.  Blue Light-Promoted Cross-Coupling of α-Diazo Esters with Isocyanides: Synthesis of Ester-Functionalized Ketenimines.

Authors:  Pavel A Sakharov; Mikhail S Novikov; Tuan K Nguyen; Mikhail A Kinzhalov; Alexander F Khlebnikov; Nikolai V Rostovskii
Journal:  ACS Omega       Date:  2022-03-03

5.  Recyclable iron(ii) caffeine-derived ionic salt catalyst in the Diels-Alder reaction of cyclopentadiene and α,β-unsaturated N-acyl-oxazolidinones in dimethyl carbonate.

Authors:  Di Meng; Dazhi Li; Thierry Ollevier
Journal:  RSC Adv       Date:  2019-07-15       Impact factor: 4.036

6.  Visible Light Induced Metal-Free Carbene N-Carbazolation.

Authors:  Claire Empel; Frederic W Patureau; Rene M Koenigs
Journal:  J Org Chem       Date:  2019-08-15       Impact factor: 4.354
  6 in total

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