Literature DB >> 29024272

Ligand- and Solvent-Controlled Regio- and Chemodivergent Carbonylative Reactions.

Jin-Bao Peng1, Xiao-Feng Wu1,2.   

Abstract

The development of highly selective procedures is one of the core goals in organic chemistry. Among the known organic transformations, carbonylation reactions present an ideal choice for the preparation of carbonyl-containing compounds. In this review, the recent achievements on the control of the selectivity for carbonylation reactions have been summarized. The effects of ligands, solvents, and bases on the selectivity are been discussed.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords:  carbon monoxide; carbonylation; selectivity; synthetic methods; transition metals

Year:  2018        PMID： 29024272     DOI： 10.1002/anie.201709807

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Synthesis of 3-Alkylideneisoindolin-1-ones via Sonogashira Cyclocarbonylative Reactions of 2-Ethynylbenzamides.

Authors:  Gianluigi Albano; Stefano Giuntini; Laura Antonella Aronica
Journal:  J Org Chem       Date:  2020-07-14       Impact factor: 4.354

2.  Site-Selective Double and Tetracyclization Routes to Fused Polyheterocyclic Structures by Pd-Catalyzed Carbonylation Reactions.

Authors:  Francesco Pancrazzi; Nicolò Sarti; Paolo P Mazzeo; Alessia Bacchi; Carla Carfagna; Raffaella Mancuso; Bartolo Gabriele; Mirco Costa; András Stirling; Nicola Della Ca'
Journal:  Org Lett       Date:  2020-02-03       Impact factor: 6.005

3.  Nickel-Catalyzed Carbonylative Synthesis of Functionalized Alkyl Iodides.

Authors:  Jin-Bao Peng; Fu-Peng Wu; Cong Xu; Xinxin Qi; Jun Ying; Xiao-Feng Wu
Journal:  iScience       Date:  2018-10-04

4.  Base-Promoted Chemodivergent Formation of 1,4-Benzoxazepin-5(4H)-ones and 1,3-Benzoxazin-4(4H)-ones Switched by Solvents.

Authors:  Qian Chen; Yunpeng Wang; Ruimao Hua
Journal:  Molecules       Date:  2019-10-19       Impact factor: 4.411

5.  Rhodium-catalyzed reductive carbonylation of aryl iodides to arylaldehydes with syngas.

Authors:  Zhenghui Liu; Peng Wang; Zhenzhong Yan; Suqing Chen; Dongkun Yu; Xinhui Zhao; Tiancheng Mu
Journal:  Beilstein J Org Chem       Date:  2020-04-08       Impact factor: 2.883

6.  Ligand-controlled regioselective and chemodivergent defluorinative functionalization of gem-difluorocyclopropanes with simple ketones.

Authors:  Leiyang Lv; Huijun Qian; Yangyang Ma; Shiqing Huang; Xiaoyu Yan; Zhiping Li
Journal:  Chem Sci       Date:  2021-11-08       Impact factor: 9.825

7.  Catalyst-controlled selective borocarbonylation of benzylidenecyclopropanes: regiodivergent synthesis of γ-vinylboryl ketones and β-cyclopropylboryl ketones.

Authors:  Fu-Peng Wu; Xiao-Feng Wu
Journal:  Chem Sci       Date:  2022-03-21       Impact factor: 9.825

8.  Preparation of Functionalized Amides Using Dicarbamoylzincs.

Authors:  Dimitrije Djukanovic; Maximilian A Ganiek; Kohei Nishi; Konstantin Karaghiosoff; Kazushi Mashima; Paul Knochel
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-13       Impact factor: 16.823
  8 in total

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