Literature DB >> 28984320

The first organocatalytic, ortho-regioselective inverse-electron-demand hetero-Diels-Alder reaction.

Joanna Hejmanowska1, Marcin Jasiński, Jakub Wojciechowski, Grzegorz Mlostoń, Łukasz Albrecht.   

Abstract

The development of the unprecedented ortho-regioselective inverse-electron-demand hetero-Diels-Alder (IEDHDA) reaction is described. It has been demonstrated that by proper choice of reactants and reaction conditions the inverse-electron-demand hetero-Diels-Alder cycloaddition can be realized with unprecedented regioselectivity arising from the reaction between the terminal carbon atom of the dienophile and the heteroatom of the heterodiene.

Entities:  

Year:  2017        PMID: 28984320     DOI: 10.1039/c7cc06518c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Lewis-Acid-Catalyzed (3+2)-Cycloadditions of Donor-Acceptor Cyclopropanes with Thioketenes.

Authors:  Grzegorz Mlostoń; Mateusz Kowalczyk; André U Augustin; Peter G Jones; Daniel B Werz
Journal:  European J Org Chem       Date:  2021-08-25

2.  First thia-Diels-Alder reactions of thiochalcones with 1,4-quinones.

Authors:  Grzegorz Mlostoń; Katarzyna Urbaniak; Paweł Urbaniak; Anna Marko; Anthony Linden; Heinz Heimgartner
Journal:  Beilstein J Org Chem       Date:  2018-07-19       Impact factor: 2.883

3.  The [4+2]-Cycloaddition of α-Nitrosoalkenes with Thiochalcones as a Prototype of Periselective Hetero-Diels-Alder Reactions-Experimental and Computational Studies.

Authors:  Grzegorz Mlostoń; Katarzyna Urbaniak; Marcin Jasiński; Ernst-Ulrich Würthwein; Heinz Heimgartner; Reinhold Zimmer; Hans-Ulrich Reissig
Journal:  Chemistry       Date:  2019-11-22       Impact factor: 5.236

4.  Allylic-Allylic Alkylation with 3,5-Dimethyl-4-nitroisoxazole: A Route to Dicarboxylic Acid Derivatives.

Authors:  Dorota Kowalczyk-Dworak; Marcin Kwit; Łukasz Albrecht
Journal:  J Org Chem       Date:  2020-02-20       Impact factor: 4.354

  4 in total

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