Literature DB >> 28967992

Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst.

Amit Kumar1, Noel Angel Espinosa-Jalapa1, Gregory Leitus2, Yael Diskin-Posner2, Liat Avram2, David Milstein1.   

Abstract

The first example of base-metal-catalysed synthesis of amides from the coupling of primary amines with either alcohols or esters is reported. The reactions are catalysed by a new manganese pincer complex and generate hydrogen gas as the sole byproduct, thus making the overall process atom-economical and sustainable.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  amides; amines; ligand design; manganese; structure elucidation

Year:  2017        PMID： 28967992     DOI： 10.1002/anie.201709180

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  Oxidative Amide Coupling from Functionally Diverse Alcohols and Amines Using Aerobic Copper/Nitroxyl Catalysis.

Authors:  Paige E Piszel; Aristidis Vasilopoulos; Shannon S Stahl
Journal:  Angew Chem Int Ed Engl       Date:  2019-07-24       Impact factor: 15.336

2.  Aminotriazole Mn(I) Complexes as Effective Catalysts for Transfer Hydrogenation of Ketones.

Authors:  Oriol Martínez-Ferraté; Christophe Werlé; Giancarlo Franciò; Walter Leitner
Journal:  ChemCatChem       Date:  2018-10-11       Impact factor: 5.686

3.  Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols.

Authors:  Subrata Chakraborty; Prosenjit Daw; Yehoshoa Ben David; David Milstein
Journal:  ACS Catal       Date:  2018-10-02       Impact factor: 13.084

4.  Development and mechanistic investigation of the manganese(iii) salen-catalyzed dehydrogenation of alcohols.

Authors:  Simone V Samuelsen; Carola Santilli; Mårten S G Ahlquist; Robert Madsen
Journal:  Chem Sci       Date:  2018-11-13       Impact factor: 9.825

5.  Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight.

Authors:  Sayan Kar; Michael Rauch; Amit Kumar; Gregory Leitus; Yehoshoa Ben-David; David Milstein
Journal:  ACS Catal       Date:  2020-04-21       Impact factor: 13.084

6.  Hydrogenative Depolymerization of Nylons.

Authors:  Amit Kumar; Niklas von Wolff; Michael Rauch; You-Quan Zou; Guy Shmul; Yehoshoa Ben-David; Gregory Leitus; Liat Avram; David Milstein
Journal:  J Am Chem Soc       Date:  2020-08-11       Impact factor: 15.419

7.  Direct synthesis of amides and imines by dehydrogenative homo or cross-coupling of amines and alcohols catalyzed by Cu-MOF.

Authors:  Soheil Zamani Anbardan; Javad Mokhtari; Ahmad Yari; Abolfazl Hassani Bozcheloei
Journal:  RSC Adv       Date:  2021-06-10       Impact factor: 4.036
  7 in total

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