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Literature DB >> 28956560

Ruthenium(ii) complexes of pyridinol and N-heterocyclic carbene derived pincers as robust catalysts for selective carbon dioxide reduction.

Chance M Boudreaux¹, Nalaka P Liyanage, Hunter Shirley, Sopheavy Siek, Deidra L Gerlach, Fengrui Qu, Jared H Delcamp, Elizabeth T Papish.

Abstract

A new pincer ligand with N-heterocyclic carbene (NHC) and 4-pyridinol-derived rings supports ruthenium complexes for photocatalytic CO2 reduction. The methoxy group on the pyridine ring offers unique catalysis advantages not seen with the unsubstituted analog. Our best catalyst offers selective CO formation, ∼250 turnover cycles, and a 40 h lifetime.

Entities: Chemical Disease

Year: 2017 PMID： 28956560 DOI： 10.1039/c7cc05706g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

3 in total

1. Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO₂ photoreduction in a noble-metal-free system.

Authors: Hai-Hua Huang; Ji-Hong Zhang; Miao Dai; Lianglin Liu; Zongren Ye; Jiahao Liu; Di-Chang Zhong; Jia-Wei Wang; Cunyuan Zhao; Zhuofeng Ke
Journal: Proc Natl Acad Sci U S A Date: 2022-08-23 Impact factor: 12.779

2. Pyridyl CO₂ Fixation Enabled by a Secondary Hydrogen Bonding Coordination Sphere.

Authors: Jacqueline N Gayton; Qing Li; Lakeeta Sanders; Roberta R Rodrigues; Glake Hill; Jared H Delcamp
Journal: ACS Omega Date: 2020-05-11

3. 2,6-Dicyano-4-pyrone as a Novel and Multifarious Building Block for the Synthesis of 2,6-Bis(hetaryl)-4-pyrones and 2,6-Bis(hetaryl)-4-pyridinols.

Authors: Dmitrii L Obydennov; Alena E Simbirtseva; Sergey E Piksin; Vyacheslav Y Sosnovskikh
Journal: ACS Omega Date: 2020-12-15

3 in total

Ruthenium(ii) complexes of pyridinol and N-heterocyclic carbene derived pincers as robust catalysts for selective carbon dioxide reduction.

1. Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO2 photoreduction in a noble-metal-free system.

2. Pyridyl CO2 Fixation Enabled by a Secondary Hydrogen Bonding Coordination Sphere.

3. 2,6-Dicyano-4-pyrone as a Novel and Multifarious Building Block for the Synthesis of 2,6-Bis(hetaryl)-4-pyrones and 2,6-Bis(hetaryl)-4-pyridinols.

1. Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO₂ photoreduction in a noble-metal-free system.

2. Pyridyl CO₂ Fixation Enabled by a Secondary Hydrogen Bonding Coordination Sphere.