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Literature DB >> 28953365

Direct β-Selective Hydrocarboxylation of Styrenes with CO₂ Enabled by Continuous Flow Photoredox Catalysis.

Hyowon Seo¹, Aofei Liu¹, Timothy F Jamison¹.

Abstract

The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO2 has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as α-substituted and β-substituted styrenes.

Entities: Chemical

Year: 2017 PMID： 28953365 DOI： 10.1021/jacs.7b05942

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

13 in total

Review 1. Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry.

Authors: Laura Buglioni; Fabian Raymenants; Aidan Slattery; Stefan D A Zondag; Timothy Noël
Journal: Chem Rev Date: 2021-08-10 Impact factor: 60.622

Review 2. Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.

Authors: Philip R D Murray; James H Cox; Nicholas D Chiappini; Casey B Roos; Elizabeth A McLoughlin; Benjamin G Hejna; Suong T Nguyen; Hunter H Ripberger; Jacob M Ganley; Elaine Tsui; Nick Y Shin; Brian Koronkiewicz; Guanqi Qiu; Robert R Knowles
Journal: Chem Rev Date: 2021-11-23 Impact factor: 60.622

3. CuH-Catalyzed Regio- and Enantioselective Hydrocarboxylation of Allenes: Toward Carboxylic Acids with Acyclic Quaternary Centers.

Authors: Sheng Feng; Stephen L Buchwald
Journal: J Am Chem Soc Date: 2021-03-24 Impact factor: 15.419

Direct β-Selective Hydrocarboxylation of Styrenes with CO₂ Enabled by Continuous Flow Photoredox Catalysis.

Review 1. Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry.

Review 2. Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.

3. CuH-Catalyzed Regio- and Enantioselective Hydrocarboxylation of Allenes: Toward Carboxylic Acids with Acyclic Quaternary Centers.

4. Visible light-promoted CO₂ fixation with imines to synthesize diaryl α-amino acids.

Review 5. Toward ideal carbon dioxide functionalization.

6. Site-Selective, Remote sp³ C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis.

7. Radical Chain Reduction via Carbon Dioxide Radical Anion (CO₂^•-).

Review 8. New Redox Strategies in Organic Synthesis by Means of Electrochemistry and Photochemistry.

9. Electrochemical β-Selective Hydrocarboxylation of Styrene Using CO₂ and Water.

10. Catalytic Generation and Use of Ketyl Radical from Unactivated Aliphatic Carbonyl Compounds.

Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis.

Review 1. Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry.

Review 2. Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.

3. CuH-Catalyzed Regio- and Enantioselective Hydrocarboxylation of Allenes: Toward Carboxylic Acids with Acyclic Quaternary Centers.

4. Visible light-promoted CO2 fixation with imines to synthesize diaryl α-amino acids.

Review 5. Toward ideal carbon dioxide functionalization.

6. Site-Selective, Remote sp3 C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis.

7. Radical Chain Reduction via Carbon Dioxide Radical Anion (CO2•-).

Review 8. New Redox Strategies in Organic Synthesis by Means of Electrochemistry and Photochemistry.

9. Electrochemical β-Selective Hydrocarboxylation of Styrene Using CO2 and Water.

10. Catalytic Generation and Use of Ketyl Radical from Unactivated Aliphatic Carbonyl Compounds.

Direct β-Selective Hydrocarboxylation of Styrenes with CO₂ Enabled by Continuous Flow Photoredox Catalysis.

4. Visible light-promoted CO₂ fixation with imines to synthesize diaryl α-amino acids.

6. Site-Selective, Remote sp³ C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis.

7. Radical Chain Reduction via Carbon Dioxide Radical Anion (CO₂^•-).

9. Electrochemical β-Selective Hydrocarboxylation of Styrene Using CO₂ and Water.