Literature DB >> 28951917

Facile preparation and dehydrogenation of unsolvated KB3H8.

Xiongfei Zheng1, Yanjing Yang, Fengqi Zhao, Fang Fang, Yanhui Guo.   

Abstract

An efficient synthesis of unsolvated KB3H8 was achieved by the reaction of a liquid K-Na alloy with BH3·THF at room temperature. KB3H8 was found to release hydrogen and minor boranes by subsequent cleavage of its B-H and B-H-B bonds during pyrolysis, and yield K2B12H12 as a major product.

Entities:  

Year:  2017        PMID: 28951917     DOI: 10.1039/c7cc06414d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Interplay between the Reorientational Dynamics of the B3H8 - Anion and the Structure in KB3H8.

Authors:  M S Andersson; J B Grinderslev; X-M Chen; X Chen; U Häussermann; W Zhou; T R Jensen; M Karlsson; T J Udovic
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2021-02-16       Impact factor: 4.126

  1 in total

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