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Literature DB >> 28936508

Rapid and ordered carbonylation and oxygenation of a cobalt(ii) methyl.

Regina R Reinig¹, Ellie L Fought, Arkady Ellern, Theresa L Windus, Aaron D Sadow.

Abstract

The oxidative carbonylation of ToMCoMe (1; ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) involves its rapid, reversible reaction with CO to form ToMCo{C(O)Me}CO (2) followed by rapid reaction with O2 yielding ToMCoOAc (3), in contrast to the slow direct carboxylation of ToMCoMe by CO2.

Entities: Chemical Gene

Year: 2017 PMID： 28936508 DOI： 10.1039/c7cc06339c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

1 in total

1. Cobalt(II) Complexes with N,N,N-Scorpionates and Bidentate Ligands: Comparison of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Tp* vs. Phenyltris(4,4-dimethyloxazolin-2-yl)borate To^M to Control the Structural Properties and Reactivities of Cobalt Centers.

Authors: Toshiki Nishiura; Takahiro Uramoto; Yuichiro Takiyama; Jun Nakazawa; Shiro Hikichi
Journal: Molecules Date: 2018-06-16 Impact factor: 4.411

1 in total

Rapid and ordered carbonylation and oxygenation of a cobalt(ii) methyl.

1. Cobalt(II) Complexes with N,N,N-Scorpionates and Bidentate Ligands: Comparison of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Tp* vs. Phenyltris(4,4-dimethyloxazolin-2-yl)borate ToM to Control the Structural Properties and Reactivities of Cobalt Centers.

1. Cobalt(II) Complexes with N,N,N-Scorpionates and Bidentate Ligands: Comparison of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Tp* vs. Phenyltris(4,4-dimethyloxazolin-2-yl)borate To^M to Control the Structural Properties and Reactivities of Cobalt Centers.