Near-Infrared-Absorbing Metal-Free Organic, Porphyrin, and Phthalocyanine Sensitizers for Panchromatic Dye-Sensitized Solar Cells.

Dye-sensitized solar cells (DSCs) are a promising source of renewable energy. However, the power conversion efficiency (PCE) of devices has been limited largely by the difficulty of producing electricity using photons from the near-infrared (NIR) spectral region. Metal-free organic sensitizers frequently employ strong electron-donating or -withdrawing moieties to tune the optical band gap to allow the absorption of lower energy wavelengths in charge-transfer systems, whereas porphyrins and phthalocyanines use substituents to shift the Soret and Q bands toward lower energy absorption. Very few devices employing precious metal-free dyes have achieved panchromatic and NIR photon conversion for electricity generation at wavelengths >750 nm despite a tremendous number of sensitizers published over the last 25 years. This Minireview seeks to compile a summary of these sensitizers to encourage assimilation, analysis, and development of efficient future sensitizers with absorption extending into the NIR. Herein, we discuss common synthetic strategies, optical properties, and electronic properties of the most successful panchromatic organic sensitizers.