| Literature DB >> 28926273 |
Yohei Ogiwara1, Kazuya Sato1, Norio Sakai1.
Abstract
A palladium-catalyzed intramolecular reaction of carboxylic acids and alkynes in a novel cyclization manner was developed. This unique cyclization efficiently provided a wide range of complex ring systems-vinyl dioxanones bearing a quaternary allylic carbon. Mechanistic studies suggest an allenyl carboxylate as an intermediate.Entities:
Year: 2017 PMID： 28926273 DOI： 10.1021/acs.orglett.7b02572
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005