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Literature DB >> 28910095

Signature of Metallic Behavior in the Metal-Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu).

Jin-Hu Dou¹, Lei Sun¹, Yicong Ge¹, Wenbin Li², Christopher H Hendon¹, Ju Li³, Sheraz Gul⁴, Junko Yano⁴, Eric A Stach⁵, Mircea Dincă¹.

Abstract

The two-dimensionally connected metal-organic frameworks (MOFs) Ni3(HIB)2 and Cu3(HIB)2 (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both materials the Fermi energy lies in a partially filled delocalized band. Together with additional structural characterization and microscopy data, these results represent the first report of metallic behavior and permanent porosity coexisting within a metal-organic framework.

Entities: Chemical

Year: 2017 PMID： 28910095 DOI： 10.1021/jacs.7b07234

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

18 in total

1. Porous lanthanide metal-organic frameworks with metallic conductivity.

Authors: Grigorii Skorupskii; Khoa N Le; Dmitri Leo Mesoza Cordova; Luming Yang; Tianyang Chen; Christopher H Hendon; Maxx Q Arguilla; Mircea Dincă
Journal: Proc Natl Acad Sci U S A Date: 2022-08-15 Impact factor: 12.779

2. Construction of conducting bimetallic organic metal chalcogenides via selective metal metathesis and oxidation transformation.

Authors: Yigang Jin; Yuhui Fang; Ze Li; Xiang Hao; Feng He; Bo Guan; Dongwei Wang; Sha Wu; Yang Li; Caiming Liu; Xiaojuan Dai; Ye Zou; Yimeng Sun; Wei Xu
Journal: Nat Commun Date: 2022-10-22 Impact factor: 17.694

3. Valence-Dependent Electrical Conductivity in a 3D Tetrahydroxyquinone-Based Metal-Organic Framework.

Authors: Gan Chen; Leland B Gee; Wenqian Xu; Yanbing Zhu; Juan S Lezama-Pacheco; Zhehao Huang; Zongqi Li; Jeffrey T Babicz; Snehashis Choudhury; Ting-Hsiang Chang; Evan Reed; Edward I Solomon; Zhenan Bao
Journal: J Am Chem Soc Date: 2020-12-14 Impact factor: 15.419

4. Modular O₂ electroreduction activity in triphenylene-based metal-organic frameworks.

Authors: Elise M Miner; Lu Wang; Mircea Dincă
Journal: Chem Sci Date: 2018-06-27 Impact factor: 9.825

5. A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior.

Authors: Renhao Dong; Zhitao Zhang; Diana C Tranca; Shengqiang Zhou; Mingchao Wang; Peter Adler; Zhongquan Liao; Feng Liu; Yan Sun; Wujun Shi; Zhe Zhang; Ehrenfried Zschech; Stefan C B Mannsfeld; Claudia Felser; Xinliang Feng
Journal: Nat Commun Date: 2018-07-06 Impact factor: 14.919

6. Integration of a (-Cu-S-)_n plane in a metal-organic framework affords high electrical conductivity.

Authors: Abhishek Pathak; Jing-Wen Shen; Muhammad Usman; Ling-Fang Wei; Shruti Mendiratta; Yu-Shin Chang; Batjargal Sainbileg; Chin-May Ngue; Ruei-San Chen; Michitoshi Hayashi; Tzuoo-Tsair Luo; Fu-Rong Chen; Kuei-Hsien Chen; Tien-Wen Tseng; Li-Chyong Chen; Kuang-Lieh Lu
Journal: Nat Commun Date: 2019-04-12 Impact factor: 14.919

Signature of Metallic Behavior in the Metal-Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu).

1. Porous lanthanide metal-organic frameworks with metallic conductivity.

2. Construction of conducting bimetallic organic metal chalcogenides via selective metal metathesis and oxidation transformation.

3. Valence-Dependent Electrical Conductivity in a 3D Tetrahydroxyquinone-Based Metal-Organic Framework.

4. Modular O₂ electroreduction activity in triphenylene-based metal-organic frameworks.

5. A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior.

6. Integration of a (-Cu-S-)_n plane in a metal-organic framework affords high electrical conductivity.

7. [Cu₃(C₆Se₆)] _n : The First Highly Conductive 2D π-d Conjugated Coordination Polymer Based on Benzenehexaselenolate.

8. Synthetic investigation of competing magnetic interactions in 2D metal-chloranilate radical frameworks.

9. Electrical Conductivity in a Porous, Cubic Rare-Earth Catecholate.

Review 10. Metal-Organic Frameworks in Modern Physics: Highlights and Perspectives.