Literature DB >> 28892634

Transition-Metal-Free Reductive Coupling of 1,3-Butadienes with Aldehydes Catalyzed by Dibutyliodotin Hydride.

Itaru Suzuki1, Yuki Uji1, Shujiro Kanaya1, Ryosuke Ieki1, Shinji Tsunoi1, Ikuya Shibata1.   

Abstract

In this study, the Bu2SnIH-catalyzed direct coupling of 1,3-dienes with aldehydes was developed. This reaction could be suitable for coupling without the use of transition-metal catalysts. Many types of aldehydes were applied to this reaction. The addition of MeOH promoted the catalytic cycle.

Entities:  

Year:  2017        PMID: 28892634     DOI: 10.1021/acs.orglett.7b02671

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Catalytic Annulation of Epoxides with Heterocumulenes by the Indium-Tin System.

Authors:  Itaru Suzuki; Akira Imakuni; Akio Baba; Ikuya Shibata
Journal:  Molecules       Date:  2018-03-28       Impact factor: 4.411

2.  Direct use of 1,3-dienes for the allylation of ketones via catalytic hydroindation.

Authors:  Itaru Suzuki; Kensuke Yagi; Shinji Miyamoto; Ikuya Shibata
Journal:  RSC Adv       Date:  2020-02-06       Impact factor: 4.036

  2 in total

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