Literature DB >> 28890579

Gold Catalysis-Facilitated Rapid Synthesis of the Daphnane/Tigliane Tricyclic Core.

Yong Li1, Mufeng Wei2, Mingji Dai1.   

Abstract

A concise approach to synthesize the 5-7-6 tricyclic carbon skeleton of the daphnane/tigliane diterpene natural products has been accomplished via a sequential gold-catalyzed furan formation and furan-allene [4+3] cycloaddition. This work provides new avenues for rapid and diverted synthesis of the medicinally important daphnane/tigliane diterpenes and their unnatural analogues.

Entities:  

Keywords:  Daphnane/Tigliane; Diterpene; Furan formation; Gold catalysis; [4+3] cycloaddition

Year:  2016        PMID： 28890579      PMCID： PMC5588696          DOI： 10.1016/j.tet.2016.11.005

Source DB:  PubMed          Journal:  Tetrahedron        ISSN： 0040-4020            Impact factor:   2.457


  37 in total

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Review 3.  Protein kinase C: structural and spatial regulation by phosphorylation, cofactors, and macromolecular interactions.

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Authors:  K Lee; J K Cha
Journal:  J Am Chem Soc       Date:  2001-06-13       Impact factor: 15.419

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Authors:  G L Carroll; R D Little
Journal:  Org Lett       Date:  2000-09-07       Impact factor: 6.005

6.  Kirkinine, a new daphnane orthoester with potent neurotrophic activity from Synaptolepis kirkii.

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Journal:  J Nat Prod       Date:  2000-09       Impact factor: 4.050

Review 7.  Relativistic effects in homogeneous gold catalysis.

Authors:  David J Gorin; F Dean Toste
Journal:  Nature       Date:  2007-03-22       Impact factor: 49.962

8.  Facile entry to the tetracyclic 5-7-6-3 tigliane ring system.

Authors:  T V Ovaska; S E Reisman; M A Flynn
Journal:  Org Lett       Date:  2001-01-11       Impact factor: 6.005

9.  Diastereoselective phenol para-alkylation: access to a cross-conjugated cyclohexadienone en route to resiniferatoxin.

Authors:  Tobias Ritter; Pablo Zarotti; Erick M Carreira
Journal:  Org Lett       Date:  2004-11-11       Impact factor: 6.005

10.  An allenic Pauson-Khand-type reaction: a reversal in pi-bond selectivity and the formation of seven-membered rings.

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Journal:  Org Lett       Date:  2002-05-30       Impact factor: 6.005
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  3 in total

1.  Total Syntheses of the Reported Structures of Curcusones I and J through Tandem Gold Catalysis.

Authors:  Yong Li; Mingji Dai
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-10       Impact factor: 15.336

Review 2.  Cross-coupling reactions towards the synthesis of natural products.

Authors:  Shaheera Tabassum; Ameer Fawad Zahoor; Sajjad Ahmad; Razia Noreen; Samreen Gul Khan; Hamad Ahmad
Journal:  Mol Divers       Date:  2021-02-20       Impact factor: 2.943

Review 3.  Recent Advances in Construction of Polycyclic Natural Product Scaffolds via One-Pot Reactions Involving Alkyne Annulation.

Authors:  Liyao Zheng; Ruimao Hua
Journal:  Front Chem       Date:  2020-10-15       Impact factor: 5.221
  3 in total

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