Literature DB >> 28885837

Selective Derivatization of a Hexaphosphane from Functionalization of White Phosphorus.

Felix Hennersdorf1, Julia Frötschel1, Jan J Weigand1.   

Abstract

The reaction of LGa (L = Dipp(4-(Dipp-imino)pent-2-en-2-yl)amide; Dipp: 2,6-diisopropylphenyl) and white phosphorus was revisited. A plethora of unprecedented polyphosphanes in addition to the known monoinserted product LGaP4 (1) are observed. An optimized synthesis of the hitherto unknown hexaphosphane (LGa)2P6 (3) is presented, and its subsequent selective derivatization with Brønsted acids, MeOTf, Ph2ECl (E = P, As), and NaOCP provides access to a wealth of functionalized hexa- and heptaphosphanes.

Entities:  

Year:  2017        PMID： 28885837     DOI： 10.1021/jacs.7b07704

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)2OCP][OCP].

Authors:  Jacob E Walley; Levi S Warring; Erik Kertész; Guocang Wang; Diane A Dickie; Zoltán Benkő; Robert J Gilliard
Journal:  Inorg Chem       Date:  2021-03-09       Impact factor: 5.165

2.  Conversion of E4 (E4 =P4 , As4 , AsP3 ) by Ni(0) and Ni(I) Synthons - A Comparative Study.

Authors:  Maria Haimerl; Christian Graßl; Michael Seidl; Martin Piesch; Manfred Scheer
Journal:  Chemistry       Date:  2021-11-23       Impact factor: 5.020

3.  Synthesis of a Cyclic Co2Sn2 Cluster Using a Co- Synthon.

Authors:  Christian M Hoidn; Christian Rödl; Madison L McCrea-Hendrick; Theresa Block; Rainer Pöttgen; Andreas W Ehlers; Philip P Power; Robert Wolf
Journal:  J Am Chem Soc       Date:  2018-10-05       Impact factor: 15.419

4.  First experimental evidence for the elusive tetrahedral cations [EP3]+ (E = S, Se, Te) in the condensed phase.

Authors:  Philippe Weis; David Christopher Röhner; Richard Prediger; Burkhard Butschke; Harald Scherer; Stefan Weber; Ingo Krossing
Journal:  Chem Sci       Date:  2019-10-07       Impact factor: 9.825

5.  Selective [2+1+1] Fragmentation of P4 by heteroleptic Metallasilylenes.

Authors:  Juliane Schoening; Alexander Gehlhaar; Christoph Wölper; Stephan Schulz
Journal:  Chemistry       Date:  2022-06-23       Impact factor: 5.020

6.  Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene.

Authors:  Daniel W N Wilson; Mauricio P Franco; William K Myers; John E McGrady; Jose M Goicoechea
Journal:  Chem Sci       Date:  2019-12-02       Impact factor: 9.825

7.  Transformations of the cyclo-P4 ligand in [Cp'''Co(η4-P4)].

Authors:  Martin Piesch; Michael Seidl; Manfred Scheer
Journal:  Chem Sci       Date:  2020-05-25       Impact factor: 9.825

8.  Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt.

Authors:  Christoph G P Ziegler; Thomas M Maier; Stefan Pelties; Clemens Taube; Felix Hennersdorf; Andreas W Ehlers; Jan J Weigand; Robert Wolf
Journal:  Chem Sci       Date:  2018-12-04       Impact factor: 9.825

9.  Insertion of Phosphenium Ions into a Bicyclo[1.1.0]Tetraphosphabutane Iron Complex.

Authors:  Martin Weber; Gábor Balázs; Alexander V Virovets; Eugenia Peresypkina; Manfred Scheer
Journal:  Molecules       Date:  2021-06-26       Impact factor: 4.411
  9 in total

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