Literature DB >> 28885010

Synthesis, Structure and Reactivity of a Borylene Cation [(NHSi)2B(CO)]+ Stabilized by Three Neutral Ligands.

Hao Wang1, Linlin Wu2, Zhenyang Lin2, Zuowei Xie1.   

Abstract

A borylene cation stabilized by bis(silylene) and carbon monoxide was prepared and structurally characterized via the reaction of bis(silylene)-stabilized bromoborylene with W(CO)6. This is the first example of a borylene cation coordinated by three neutral ligands, which can be viewed as a cationic form of a long-sought Lewis base-stabilized zerovalent boron compound. This cation can cleave dihydrogen.

Entities:  

Year:  2017        PMID： 28885010     DOI： 10.1021/jacs.7b08667

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes.

Authors:  Merle Arrowsmith; Julia I Schweizer; Myron Heinz; Marcel Härterich; Ivo Krummenacher; Max C Holthausen; Holger Braunschweig
Journal:  Chem Sci       Date:  2019-04-08       Impact factor: 9.825

2.  A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability.

Authors:  Chonghe Zhang; Xiaocui Liu; Junyi Wang; Qing Ye
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-29       Impact factor: 16.823

3.  Bis(silylene)-Stabilized Monovalent Nitrogen Complexes.

Authors:  Shenglai Yao; Tibor Szilvási; Yun Xiong; Christian Lorent; Ales Ruzicka; Matthias Driess
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-28       Impact factor: 15.336
  3 in total

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