| Literature DB >> 28872178 |
Xiao Han1, Qing Cheng, Xiangru Meng, Zhichao Shao, Ke Ma, Donghui Wei, Jie Ding, Hongwei Hou.
Abstract
The first example of micro-adjustments of a metal organic framework (MOF) structure was observed in a new Zn(ii) MOF (Zn-BTDC-M1) derived from a benzothiadiazole-4,7-dicarboxylic acid (H2BTDC) ligand using a light-driven decarboxylation process. Interestingly, such decarboxylation occurs at the non-chelated wing of the ligand, which induced a change in the capability of the MOF for physical N2 adsorption and chemical NH3 gas adsorption.Entities:
Year: 2017 PMID： 28872178 DOI： 10.1039/c7cc06125k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222