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Literature DB >> 28860354

Comment on "Active sites for CO₂ hydrogenation to methanol on Cu/ZnO catalysts".

Junji Nakamura¹, Tadahiro Fujitani², Sebastian Kuld³, Stig Helveg³, Ib Chorkendorff⁴, Jens Sehested⁵.

Abstract

Kattel et al (Reports, 24 March 2017, p. 1296) report that a zinc on copper (Zn/Cu) surface undergoes oxidation to zinc oxide/copper (ZnO/Cu) during carbon dioxide (CO2) hydrogenation to methanol and conclude that the Cu-ZnO interface is the active site for methanol synthesis. Similar experiments conducted two decades ago by Fujitani and Nakamura et al demonstrated that Zn is attached to formate rather than being fully oxidized.

Entities: Chemical

Mesh：

Substances：
Zinc Oxide
Methanol

Year: 2017 PMID： 28860354 DOI： 10.1126/science.aan8074

Source DB: PubMed Journal: Science ISSN： 0036-8075 Impact factor: 47.728

Keyword Cloud
Cited

4 in total

1. Insight into the Nature of the ZnO _x Promoter during Methanol Synthesis.

Authors: Remco Dalebout; Laura Barberis; Giorgio Totarella; Savannah J Turner; Camille La Fontaine; Frank M F de Groot; Xavier Carrier; Ad M J van der Eerden; Florian Meirer; Petra E de Jongh
Journal: ACS Catal Date: 2022-05-20 Impact factor: 13.700

Review 2. Accelerating photo-thermal CO₂ reduction to CO, CH₄ or methanol over metal/oxide semiconductor catalysts.

Authors: Kristijan Lorber; Petar Djinović
Journal: iScience Date: 2022-03-18

3. ZnO-ZnCr₂O₄ composite prepared by a glycine nitrate process method and applied for hydrogen production by steam reforming of methanol.

Authors: Chung-Lun Yu; Subramanian Sakthinathan; Guan-Ting Lai; Chia-Cheng Lin; Te-Wei Chiu; Ming-Che Liu
Journal: RSC Adv Date: 2022-08-10 Impact factor: 4.036

4. The unique interplay between copper and zinc during catalytic carbon dioxide hydrogenation to methanol.

Authors: Maxim Zabilskiy; Vitaly L Sushkevich; Dennis Palagin; Mark A Newton; Frank Krumeich; Jeroen A van Bokhoven
Journal: Nat Commun Date: 2020-05-15 Impact factor: 14.919

4 in total

Comment on "Active sites for CO2 hydrogenation to methanol on Cu/ZnO catalysts".

1. Insight into the Nature of the ZnO x Promoter during Methanol Synthesis.

Review 2. Accelerating photo-thermal CO2 reduction to CO, CH4 or methanol over metal/oxide semiconductor catalysts.

3. ZnO-ZnCr2O4 composite prepared by a glycine nitrate process method and applied for hydrogen production by steam reforming of methanol.

4. The unique interplay between copper and zinc during catalytic carbon dioxide hydrogenation to methanol.

Comment on "Active sites for CO₂ hydrogenation to methanol on Cu/ZnO catalysts".

1. Insight into the Nature of the ZnO _x Promoter during Methanol Synthesis.

Review 2. Accelerating photo-thermal CO₂ reduction to CO, CH₄ or methanol over metal/oxide semiconductor catalysts.

3. ZnO-ZnCr₂O₄ composite prepared by a glycine nitrate process method and applied for hydrogen production by steam reforming of methanol.