| Literature DB >> 28849839 |
Lucía García1, Khalidah H M Al Furaiji2, David J D Wilson2, Jason L Dutton2, Michael S Hill1, Mary F Mahon1.
Abstract
Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.Entities:
Year: 2017 PMID： 28849839 DOI： 10.1039/c7dt03046k
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390