| Literature DB >> 28841312 |
Mohammed H Al-Huniti1, Zachary B Sullivan1, Jarrod L Stanley1, James A Carson1, I F Dempsey Hyatt2, A Christina Hairston1, Mitchell P Croatt1.
Abstract
Phenylcyanocarbene was generated by the reaction of azide with a hypervalent iodonium alkynyl triflate and reacted in situ with 21 different carbocyclic and heterocyclic aromatic compounds. These reactions led to more complex products that frequently underwent subsequent rearrangements. The reactivity was further explored in a mechanistic study to ascertain the chemoselectivity and stereospecificity.Entities:
Year: 2017 PMID： 28841312 DOI： 10.1021/acs.joc.7b01608
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354