Literature DB >> 28820217

Hysteretic spin crossover driven by anion conformational change.

Natnaree Phukkaphan1, Dyanne L Cruickshank, Keith S Murray, Wasinee Phonsri, Phimphaka Harding, David J Harding.   

Abstract

A new air stable FeIII spin crossover (SCO) complex has been synthesized. The compound undergoes abrupt SCO near room temperature with T1/2 (↓) = 244 K and T1/2 (↑) = 278 K. Structural studies of the complex in the high spin and low spin state show that the strong cooperativity and thus the wide hysteresis is driven by an unprecedented anionic conformational change.

Year:  2017        PMID： 28820217     DOI： 10.1039/c7cc05998a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Structural Insights into Hysteretic Spin-Crossover in a Set of Iron(II)-2,6-bis(1H-Pyrazol-1-yl)Pyridine) Complexes.

Authors:  Nithin Suryadevara; Asato Mizuno; Lea Spieker; Soma Salamon; Stephan Sleziona; André Maas; Erik Pollmann; Benoît Heinrich; Marika Schleberger; Heiko Wende; Senthil Kumar Kuppusamy; Mario Ruben
Journal:  Chemistry       Date:  2022-01-19       Impact factor: 5.020

2.  Room temperature conductance switching in a molecular iron(iii) spin crossover junction.

Authors:  Senthil Kumar Karuppannan; Alejandro Martín-Rodríguez; Eliseo Ruiz; Phimphaka Harding; David J Harding; Xiaojiang Yu; Anton Tadich; Bruce Cowie; Dongchen Qi; Christian A Nijhuis
Journal:  Chem Sci       Date:  2020-11-10       Impact factor: 9.825
  2 in total

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