| Literature DB >> 28812879 |
Yunxia Gao1,2, Ying Yang2, Wenjun Zheng1, Yuanyuan Su1, Xiang Zhang1, Herbert W Roesky3.
Abstract
Germanium and tin monoxides (MO, M = Ge, Sn) were trapped by the 1,2,4-diazaphospholide-based germylene and stannylene M[3,5-tBu2dp]2 (M = Ge (2), Sn (3)), resulting in the Lewis acid-base adduct of composition M(μ-O)[M{η1(N)-(3,5-tBu2dp)}2]2 (M = Ge (4), Sn (5)). Compounds 4 and 5 were characterized by single-crystal X-ray structural analysis. The bonding features of 4 and 5 were supported by DFT calculations.Entities:
Year: 2017 PMID： 28812879 DOI： 10.1021/acs.inorgchem.7b00918
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165