Literature DB >> 28809553

Structure-Directing Role of Phosphonate in the Synthesis of High-Nuclearity Silver(I) Sulfide-Ethynide-Thiolate Clusters.

Jun-Ling Jin1, Yun-Peng Xie1, Han Cui2, Guang-Xiong Duan1, Xing Lu1, Thomas C W Mak3.   

Abstract

Phosphonate ligands as structure-directing components have been employed to construct four new high-nuclearity silver(I) sulfide-ethynide-thiolate clusters, in which silver(I) aggregates tBuC≡C⊃Ag3, tBuC≡C⊃Ag4, and 2tBuC≡C⊃Ag7 are bridged by tBuS- ligands to engender respective silver(I) ethynide-thiolate clusters functioning as integral shell components, which are supported by phosphonate ligands. In each silver(I) sulfide-ethynide-thiolate cluster, a different encapsulated silver sulfide cluster serves as a core template.

Entities:  

Year:  2017        PMID： 28809553     DOI： 10.1021/acs.inorgchem.7b01326

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  Structural Diversity of Silver Fluorinated β-Diketonates: Effect of the Terminal Substituent and Solvent.

Authors:  Evgeniia S Vikulova; Taisiya S Sukhikh; Sergey A Gulyaev; Igor Yu Ilyin; Natalia B Morozova
Journal:  Molecules       Date:  2022-01-20       Impact factor: 4.411

2.  A one-dimensional infinite silver alkynyl assembly [Ag8(C[triple bond, length as m-dash]C t Bu)5(CF3COO)3(CH3CN)] n : synthesis, crystal structure and properties.

Authors:  Ju-Feng Shi; Zhi-Jin Chen; Liu-Jie Zhang; Kun Zhou; Jiu-Yu Ji; Yan-Feng Bi
Journal:  RSC Adv       Date:  2020-04-22       Impact factor: 4.036
  2 in total

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