Literature DB >> 28795719

Titanium redox catalysis: insights and applications of an earth-abundant base metal.

Zachary W Davis-Gilbert1, Ian A Tonks.   

Abstract

π-Acid ancillary ligands, reactants, or products can stabilize reactive low valent Ti intermediates through backbonding, and present opportunities for the development of vast new classes of Ti-catalyzed redox reactions with practical applications.

Entities:  

Year:  2017        PMID： 28795719      PMCID： PMC5593795          DOI： 10.1039/c7dt02319g

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  27 in total

Review 1.  Hydroamination: direct addition of amines to alkenes and alkynes.

Authors:  Thomas E Müller; Kai C Hultzsch; Miguel Yus; Francisco Foubelo; Mizuki Tada
Journal:  Chem Rev       Date:  2008-08-26       Impact factor: 60.622

2.  First titanium-catalyzed 1,4-hydrophosphination of 1,3-dienes.

Authors:  Arnaud Perrier; Virginie Comte; Claude Moïse; Pierre Le Gendre
Journal:  Chemistry       Date:  2010-01-04       Impact factor: 5.236

3.  Titanium-catalyzed multicomponent couplings: efficient one-pot syntheses of nitrogen heterocycles.

Authors:  Aaron L Odom; Tanner J McDaniel
Journal:  Acc Chem Res       Date:  2015-08-21       Impact factor: 22.384

4.  A theoretical study on the mechanism and diastereoselectivity of the Kulinkovich hydroxycyclopropanation reaction.

Authors:  Y D Wu; Z X Yu
Journal:  J Am Chem Soc       Date:  2001-06-20       Impact factor: 15.419

5.  Quantifying ligand effects in high-oxidation-state metal catalysis.

Authors:  Brennan S Billow; Tanner J McDaniel; Aaron L Odom
Journal:  Nat Chem       Date:  2017-08-07       Impact factor: 24.427

6.  Generation of TiII Alkyne Trimerization Catalysts in the Absence of Strong Metal Reductants.

Authors:  Xin Yi See; Evan P Beaumier; Zachary W Davis-Gilbert; Peter L Dunn; Jacob A Larsen; Adam J Pearce; T Alex Wheeler; Ian A Tonks
Journal:  Organometallics       Date:  2017-03-29       Impact factor: 3.876

Review 7.  Which Metals are Green for Catalysis? Comparison of the Toxicities of Ni, Cu, Fe, Pd, Pt, Rh, and Au Salts.

Authors:  Ksenia S Egorova; Valentine P Ananikov
Journal:  Angew Chem Int Ed Engl       Date:  2016-08-17       Impact factor: 15.336

8.  N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions.

Authors:  Scott A Ryken; Laurel L Schafer
Journal:  Acc Chem Res       Date:  2015-08-06       Impact factor: 22.384

9.  Redox non-innocence permits catalytic nitrene carbonylation by (dadi)Ti[double bond, length as m-dash]NAd (Ad = adamantyl).

Authors:  Spencer P Heins; Peter T Wolczanski; Thomas R Cundari; Samantha N MacMillan
Journal:  Chem Sci       Date:  2017-03-06       Impact factor: 9.825

10.  Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes.

Authors:  Jiandong Guo; Xi Deng; Chunyu Song; Yu Lu; Shuanglin Qu; Yanfeng Dang; Zhi-Xiang Wang
Journal:  Chem Sci       Date:  2016-12-22       Impact factor: 9.825
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  8 in total

1.  Dative Directing Group Effects in Ti-Catalyzed [2+2+1] Pyrrole Synthesis: Chemo- and Regioselective Alkyne Heterocoupling.

Authors:  Hsin-Chun Chiu; Xin Yi See; Ian A Tonks
Journal:  ACS Catal       Date:  2018-11-29       Impact factor: 13.084

2.  Group 4 Diarylmetallocenes as Bespoke Aryne Precursors for Titanium-Catalyzed [2 + 2 + 2] Cycloaddition of Arynes and Alkynes.

Authors:  Benjamin R Reiner; Ian A Tonks
Journal:  Inorg Chem       Date:  2019-06-12       Impact factor: 5.165

3.  Trimethylsilyl-Protected Alkynes as Selective Cross-Coupling Partners in Titanium-Catalyzed [2+2+1] Pyrrole Synthesis.

Authors:  Hsin-Chun Chiu; Ian A Tonks
Journal:  Angew Chem Int Ed Engl       Date:  2018-04-25       Impact factor: 15.336

4.  In Situ Catalyst Generation and Benchtop-Compatible Entry Points for TiII/TiIV Redox Catalytic Reactions.

Authors:  Zachary W Davis-Gilbert; Kento Kawakita; Daniel R Blechschmidt; Hayato Tsurugi; Kazushi Mashima; Ian A Tonks
Journal:  Organometallics       Date:  2018-09-06       Impact factor: 3.876

5.  Mechanism of Ti-Catalyzed Oxidative Nitrene Transfer in [2 + 2 + 1] Pyrrole Synthesis from Alkynes and Azobenzene.

Authors:  Zachary W Davis-Gilbert; Xuelan Wen; Jason D Goodpaster; Ian A Tonks
Journal:  J Am Chem Soc       Date:  2018-05-31       Impact factor: 15.419

6.  Ti-Catalyzed Radical Alkylation of Secondary and Tertiary Alkyl Chlorides Using Michael Acceptors.

Authors:  Xiangyu Wu; Wei Hao; Ke-Yin Ye; Binyang Jiang; Gisselle Pombar; Zhidong Song; Song Lin
Journal:  J Am Chem Soc       Date:  2018-10-26       Impact factor: 15.419

7.  Generation of Masked TiII Intermediates from TiIV Amides via β-H Abstraction or Alkyne Deprotonation: An Example of Ti-Catalyzed Nitrene-Coupled Transfer Hydrogenation.

Authors:  Adam J Pearce; Yukun Cheng; Rachel J Dunscomb; Ian A Tonks
Journal:  Organometallics       Date:  2020-10-20       Impact factor: 3.876

8.  Titanium Ions Play a Synergistic Role in the Activation of NLRP3 Inflammasome in Jurkat T Cells.

Authors:  Xiao Li; Li Tang; Donghui Chen
Journal:  Inflammation       Date:  2020-08       Impact factor: 4.657
  8 in total

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