| Literature DB >> 28787842 |
Weisheng Zhao1,2, Xiaoxuan Zhao3,4, Boyu Zhang5,6, Kaihua Cao7,8, Lezhi Wang9,10, Wang Kang11,12, Qian Shi13,14, Mengxing Wang15,16, Yu Zhang17,18,19, You Wang20,21, Shouzhong Peng22,23, Jacques-Olivier Klein24, Lirida Alves de Barros Naviner25, Dafine Ravelosona26.
Abstract
Magnetic tunnel junction nanopillar with interfacial perpendicular magnetic anisotropy (PMA-MTJ) becomes a promising candidate to build up spin transfer torque magnetic random access memory (STT-MRAM) for the next generation of non-volatile memory as it features low spin transfer switching current, fast speed, high scalability, and easy integration into conventional complementary metal oxide semiconductor (CMOS) circuits. However, this device suffers from a number of failure issues, such as large process variation and tunneling barrier breakdown. The large process variation is an intrinsic issue for PMA-MTJ as it is based on the interfacial effects between ultra-thin films with few layers of atoms; the tunneling barrier breakdown is due to the requirement of an ultra-thin tunneling barrier (e.g., <1 nm) to reduce the resistance area for the spin transfer torque switching in the nanopillar. These failure issues limit the research and development of STT-MRAM to widely achieve commercial products. In this paper, we give a full analysis of failure mechanisms for PMA-MTJ and present some eventual solutions from device fabrication to system level integration to optimize the failure issues.Entities:
Keywords: STT-MRAM; barrier breakdown; interfacial perpendicular magnetic anisotropy; magnetic tunnel junction; process variation; stochastic behavior
Year: 2016 PMID: 28787842 PMCID: PMC5456535 DOI: 10.3390/ma9010041
Source DB: PubMed Journal: Materials (Basel) ISSN: 1996-1944 Impact factor: 3.623
Figure 1Magnetic tunnel junction with interfacial perpendicular magnetic anisotropy (PMA-MTJ) consists of several ultra-thin layers: two ferromagnetic layers separated by an oxide barrier. Two heavy metal layers are associated with the two ferromagnetic layers, while the synthetic antiferromagnetic (SAF) layer is inserted adjacent the reference layer and bottom electrode. With the spin transfer torque mechanism, PMA-MTJ changes between two states when a bidirectional current I is higher than the critical current I0.
Figure 2Typical flow of magnetic tunnel junction (MTJ) device fabrication, which mainly comprises stack deposition, patterning, etching dielectric encapsulation, and connecting.
Figure 3Cross-section image of MTJ stack by transmission electron microscope (TEM), which contains free and synthetic antiferromagnetic (SAF) reference layers separated by ultra-thin 0.88 nm MgO tunnel barrier. This sample was prepared by Anelva HC7100 sputtering equipment. A pinhole exists in the ultra-thinoxide barrier due to rough deposition of MgO, indicated by the red circle.
Figure 4Schematic diagram of the generation of a pinhole. It originates from the rough MgO layer, formed by CoFeB deposition upon defective MgO. The existence of pinholes shunts the current, resulting in the degradation of tunnel magneto-resistance ratio (TMR), and may even cause breakdown.
Figure 5Magnetic curves (measured by NanoMOKE) of MTJ stacks annealed at different annealing times. The film stack of substrate/Ta(3)/MgO(1)/CoFeB(1.1)/Ta(1.5)/Ru(5)/Ta(5) (units in nm) deposited by magnetic sputtering processing are ex situ annealed at 300 °C for different annealing times (40, 60 and 90 min) with perpendicular H = 0.775 T in a high vacuum chamber.
Figure 6Schematic illustration of (a) short-circuit caused by redeposition with no tilt and rotation; (b) cleaned sidewall with beam angle and rotation.
Figure 7Etching shadow effect with beam angle θ, which is defined as the angle between incident beam and the normal direction of the wafer. The minimum distance between two nanopillar is determined by the height of the pillar and the beam angle.
Figure 8Cross-section image of MTJ stack by scanning electron microscope (SEM), which is etched by inductively-coupled plasma (ICP), shows few redeposition and good device profile.
Figure 9Estimated lifetime of dielectric breakdown versus applied bias voltage with different thickness of MgO oxide barrier.
Figure 10Cross-section image of MTJ stack by transmission electron microscope (TEM), sputtered by Anelva HC7100 sputtering equipment. Multilayers with different ultra-thin MgO oxide barrier thickness: (a) 0.86 nm and (b) 1.07 nm, respectively, while the nominal thickness is 1 nm.
Figure 11Schematic of the hard failure repair technique with redundancy.
Figure 12Final failure rate after applying Error correction code (ECC) (with codeword length of 256 bits).