Literature DB >> 28787148

Cascade Polymerization via Controlled Tandem Olefin Metathesis/Metallotropic 1,3-Shift Reactions for the Synthesis of Fully Conjugated Polyenynes.

Cheol Kang1, Hyeon Park1, Jin-Kyung Lee1, Tae-Lim Choi1.   

Abstract

We demonstrate the first example of cascade polymerization by combining olefin metathesis and metallotropic 1,3-shift reactions to form unique conjugated polyenynes. Rational design of monomers enabled controlled polymerization, and kinetic investigation of the polymerization mechanism was conducted.

Entities:  

Year:  2017        PMID： 28787148     DOI： 10.1021/jacs.7b04913

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  The Introduction of the Radical Cascade Reaction into Polymer Chemistry: A One-Step Strategy for Synchronized Polymerization and Modification.

Authors:  Nengbo Zhu; Mong-Feng Chiou; Haigen Xiong; Min Su; Muqiao Su; Yajun Li; Wen-Ming Wan; Hongli Bao
Journal:  iScience       Date:  2020-02-13

2.  Resonance promoted ring-opening metathesis polymerization of twisted amides.

Authors:  Mizhi Xu; Krista K Bullard; Aja M Nicely; Will R Gutekunst
Journal:  Chem Sci       Date:  2019-08-30       Impact factor: 9.825
  2 in total

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