Literature DB >> 28783197

Efficient kinetic separation of propene and propane using two microporous metal organic frameworks.

Junjie Peng1, Hao Wang, David H Olson, Zhong Li, Jing Li.   

Abstract

An excellent performance for the kinetic separation of propene and propane is realized in two microporous MOF analogues, namely Zn(ox)0.5(trz) and Zn(ox)0.5(atrz). The great difference in diffusivity of propane and propene in Zn(ox)0.5(trz) at 323 K results in a kinetic separation factor of 1565, marking the highest value among all MOFs reported for kinetic separation of the two hydrocarbon species. The high selectivity is attributed primarily to the appropriate pore apertures.

Entities:  

Year:  2017        PMID： 28783197     DOI： 10.1039/c7cc03529b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Direct Visualization of Supramolecular Binding and Separation of Light Hydrocarbons in MFM-300(In).

Authors:  Lixia Guo; Mathew Savage; Joe H Carter; Xue Han; Ivan da Silva; Pascal Manuel; Svemir Rudić; Chiu C Tang; Sihai Yang; Martin Schröder
Journal:  Chem Mater       Date:  2022-06-06       Impact factor: 10.508

2.  Molecular Sieving of Ethane from Ethylene through the Molecular Cross-Section Size Differentiation in Gallate-based Metal-Organic Frameworks.

Authors:  Zongbi Bao; Jiawei Wang; Zhiguo Zhang; Huabin Xing; Qiwei Yang; Yiwen Yang; Hui Wu; Rajamani Krishna; Wei Zhou; Banglin Chen; Qilong Ren
Journal:  Angew Chem Int Ed Engl       Date:  2018-11-11       Impact factor: 15.336

3.  Differential guest location by host dynamics enhances propylene/propane separation in a metal-organic framework.

Authors:  Dmytro Antypov; Aleksander Shkurenko; Prashant M Bhatt; Youssef Belmabkhout; Karim Adil; Amandine Cadiau; Mikhail Suyetin; Mohamed Eddaoudi; Matthew J Rosseinsky; Matthew S Dyer
Journal:  Nat Commun       Date:  2020-11-30       Impact factor: 14.919

4.  Quasi-Orthogonal Configuration of Propylene within a Scalable Metal-Organic Framework Enables Its Purification from Quinary Propane Dehydrogenation Byproducts.

Authors:  Peng Hu; Jialang Hu; Hao Liu; Hao Wang; Jie Zhou; Rajamani Krishna; Hongbing Ji
Journal:  ACS Cent Sci       Date:  2022-07-22       Impact factor: 18.728

5.  Exploiting equilibrium-kinetic synergetic effect for separation of ethylene and ethane in a microporous metal-organic framework.

Authors:  Qi Ding; Zhaoqiang Zhang; Cong Yu; Peixin Zhang; Jun Wang; Xili Cui; Chao-Hong He; Shuguang Deng; Huabin Xing
Journal:  Sci Adv       Date:  2020-04-10       Impact factor: 14.136
  5 in total

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