Literature DB >> 28766948

Organic Dye-Catalyzed Atom Transfer Radical Addition-Elimination (ATRE) Reaction for the Synthesis of Perfluoroalkylated Alkenes.

Deo Prakash Tiwari1, Saumya Dabral1, Jian Wen1, Jan Wiesenthal1, Steven Terhorst1, Carsten Bolm1.   

Abstract

An atom transfer radical addition elimination (ATRE) reaction of terminal alkenes with perfluoroalkyl halides under visible light is described. The photoredox catalysis with Eosin Y provides perfluoroalkenes in good yields. The reaction has been utilized for the late stage perfluoroalkenylation of an estrone-derived alkene.

Entities:  

Year:  2017        PMID： 28766948     DOI： 10.1021/acs.orglett.7b01952

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Pyrene-based metal-organic framework NU-1000 photocatalysed atom-transfer radical addition for iodoperfluoroalkylation and (Z)-selective perfluoroalkylation of olefins by visible-light irradiation.

Authors:  Tiexin Zhang; Pengfang Wang; Zirui Gao; Yang An; Cheng He; Chunying Duan
Journal:  RSC Adv       Date:  2018-09-24       Impact factor: 4.036

2.  Perfluoroalkylative pyridylation of alkenes via 4-cyanopyridine-boryl radicals.

Authors:  Jia Cao; Guoqiang Wang; Liuzhou Gao; Hui Chen; Xueting Liu; Xu Cheng; Shuhua Li
Journal:  Chem Sci       Date:  2019-01-16       Impact factor: 9.825

3.  Visible-light Promoted Atom Transfer Radical Addition-Elimination (ATRE) Reaction for the Synthesis of Fluoroalkylated Alkenes Using DMA as Electron-Donor.

Authors:  Wen-Wen Xu; Le Wang; Ting Mao; Jiwei Gu; Xiao-Fei Li; Chun-Yang He
Journal:  Molecules       Date:  2020-01-24       Impact factor: 4.411

4.  Visible light-induced photocatalytic C-H ethoxycarbonylmethylation of imidazoheterocycles with ethyl diazoacetate.

Authors:  Suvam Bhattacharjee; Sudip Laru; Sadhanendu Samanta; Mukta Singsardar; Alakananda Hajra
Journal:  RSC Adv       Date:  2020-07-28       Impact factor: 4.036

5.  Palladium-catalyzed difluoroalkylative carbonylation of styrenes toward difluoropentanedioates.

Authors:  Zhi-Peng Bao; Youcan Zhang; Xiao-Feng Wu
Journal:  Chem Sci       Date:  2022-08-03       Impact factor: 9.969
  5 in total

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