| Literature DB >> 28765374 |
Tina Hecksher1, Darius H Torchinsky2, Christoph Klieber3, Jeremy A Johnson3, Jeppe C Dyre1, Keith A Nelson4.
Abstract
Diverse material classes exhibit qualitatively similar behavior when made viscous upon cooling toward the glass transition, suggesting a common theoretical basis. We used seven different measurement methods to determine the mechanical relaxation kinetics of a prototype molecular glass former over a temporal range of 13 decades and over a temperature range spanning liquid to glassy states. The data conform to time-temperature superposition for the main (alpha) process and to a scaling relation of schematic mode-coupling theory. The broadband mechanical measurements demonstrated have fundamental and practical applications in polymer science, geophysics, multifunctional materials, and other areas.Entities:
Keywords: broadband mechanical spectroscopy; mode-coupling theory; viscous liquids
Year: 2017 PMID: 28765374 PMCID: PMC5565458 DOI: 10.1073/pnas.1707251114
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN: 0027-8424 Impact factor: 11.205