Literature DB >> 28758662

The role of carbonate in electro-catalytic water oxidation by using Ni(1,4,8,11-tetraazacyclotetradecane)2.

Burg Ariela1, Wolfer Yaniv, Shamir Dror, Kornweitz Haya, Albo Yael, Maimon Eric, Meyerstein Dan.   

Abstract

NiLi2+ are good electro-catalysts for water oxidation in phosphate or carbonate buffers. The results point out that the active oxidizing agents are L(X)NiIVOH4-(3-n+1)/(2-n+1), where X = PO4Hn(3-n)- or CO3Hn(2-n)- formed from LNiIVX2via a mechanism involving an acid catalyzed O-P or O-C bond heterolysis. Carbonate behaves differently from phosphate as it is a non-innocent ligand and it can be oxidized.

Entities:  

Year:  2017        PMID： 28758662     DOI： 10.1039/c7dt02223a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  3 in total

1.  Controlling the Size and Pattern Pitch of Ni(OH)2 Nanoclusters Using Dip-Pen Nanolithography to Improve Water Oxidation.

Authors:  Zorik Shamish; Moshe Zohar; Dror Shamir; Ariela Burg
Journal:  Molecules       Date:  2020-06-26       Impact factor: 4.411

2.  The Role of Carbonate in Catalytic Oxidations.

Authors:  Shanti Gopal Patra; Amir Mizrahi; Dan Meyerstein
Journal:  Acc Chem Res       Date:  2020-09-25       Impact factor: 22.384

3.  Potential- and Buffer-Dependent Catalyst Decomposition during Nickel-Based Water Oxidation Catalysis.

Authors:  Joeri Hessels; Fengshou Yu; Remko J Detz; Joost N H Reek
Journal:  ChemSusChem       Date:  2020-10-09       Impact factor: 8.928
  3 in total

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