| Literature DB >> 28742944 |
Matteo Chierchia1, Chunyin Law1, James P Morken1.
Abstract
Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.Entities:
Keywords: asymmetric catalysis; boron; cross coupling; nickel
Year: 2017 PMID: 28742944 PMCID: PMC5699474 DOI: 10.1002/anie.201706719
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336