Literature DB >> 28742944

Nickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates.

Matteo Chierchia1, Chunyin Law1, James P Morken1.   

Abstract

Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  asymmetric catalysis; boron; cross coupling; nickel

Year:  2017        PMID: 28742944      PMCID: PMC5699474          DOI: 10.1002/anie.201706719

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  35 in total

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  15 in total

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7.  Enantioselective Synthesis of Tertiary β-Boryl Amides by Conjunctive Cross-Coupling of Alkenyl Boronates and Carbamoyl Chlorides.

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8.  Diastereoselective and Enantioselective Conjunctive Cross-Coupling Enabled by Boron Ligand Design.

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