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Literature DB >> 28731085

Heptafluoroisopropyl diazomethane (i-C₃F₇CHN₂): in situ generation and synthesis of pyrazoles.

Abstract

A novel chemical reagent - heptafluoroisopropyl diazomethane (i-C3F7CHN2) - has been generated in situ in aqueous media. It readily reacts with electron-deficient alkynes towards polyfluorinated pyrazoles that are important in agrochemistry.

Entities: Chemical

Year: 2017 PMID： 28731085 DOI： 10.1039/c7ob01579h

Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876

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Cited

2 in total

Review 1. Diazoacetonitrile (N₂ CHCN): A Long Forgotten but Valuable Reagent for Organic Synthesis.

Authors: Pavel K Mykhailiuk; Rene M Koenigs
Journal: Chemistry Date: 2019-10-15 Impact factor: 5.236

2. Stoichiometric Photochemical Carbene Transfer by Bamford-Stevens Reaction.

Authors: Sripati Jana; Fang Li; Claire Empel; Dennis Verspeek; Polina Aseeva; Rene M Koenigs
Journal: Chemistry Date: 2020-02-21 Impact factor: 5.236

2 in total

Heptafluoroisopropyl diazomethane (i-C3F7CHN2): in situ generation and synthesis of pyrazoles.

Review 1. Diazoacetonitrile (N2 CHCN): A Long Forgotten but Valuable Reagent for Organic Synthesis.

2. Stoichiometric Photochemical Carbene Transfer by Bamford-Stevens Reaction.

Heptafluoroisopropyl diazomethane (i-C₃F₇CHN₂): in situ generation and synthesis of pyrazoles.

Review 1. Diazoacetonitrile (N₂ CHCN): A Long Forgotten but Valuable Reagent for Organic Synthesis.