Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex.

Literature DB >> 28726874

New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex.

Mio Sekino¹, Hideki Furutachi, Rina Tojo, Ayumi Hishi, Hanako Kajikawa, Takatoshi Suzuki, Kaito Suzuki, Shuhei Fujinami, Shigehisa Akine, Yoko Sakata, Takehiro Ohta, Shinya Hayami, Masatatsu Suzuki.

Abstract

A (μ-peroxo)diiron(iii) complex [Fe2(LPh4)(O2)(Ph3CCO2)]2+ (1-O2) with a dinucleating ligand (LPh4), generated from the reaction of a carboxylate bridged diiron(ii) complex [Fe2(LPh4)(Ph3CCO2)]2+ (1) with dioxygen in CH2Cl2, provides a diiron(iv)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.

Entities: Chemical

Year: 2017 PMID： 28726874 DOI： 10.1039/c7cc04382a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

3 in total

1. Sc³⁺-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O₂ to Generate a Complex with an Fe^IV₂(μ-O)₂ Core.

Authors: Saikat Banerjee; Apparao Draksharapu; Patrick M Crossland; Ruixi Fan; Yisong Guo; Marcel Swart; Lawrence Que
Journal: J Am Chem Soc Date: 2020-02-19 Impact factor: 15.419

2. Generation of a μ-1,2-hydroperoxo Fe^IIIFe^III and a μ-1,2-peroxo Fe^IVFe^III Complex.

Authors: Stephan Walleck; Thomas Philipp Zimmermann; Henning Hachmeister; Christian Pilger; Thomas Huser; Sagie Katz; Peter Hildebrandt; Anja Stammler; Hartmut Bögge; Eckhard Bill; Thorsten Glaser
Journal: Nat Commun Date: 2022-03-16 Impact factor: 14.919

3. μ-Oxo-bridged diiron(iii) complexes of tripodal 4N ligands as catalysts for alkane hydroxylation reaction using m-CPBA as an oxidant: substrate vs. self hydroxylation.

Authors: Mani Balamurugan; Eringathodi Suresh; Mallayan Palaniandavar
Journal: RSC Adv Date: 2021-06-17 Impact factor: 3.361

3 in total

New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex.

1. Sc3+-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV2(μ-O)2 Core.

2. Generation of a μ-1,2-hydroperoxo FeIIIFeIII and a μ-1,2-peroxo FeIVFeIII Complex.

3. μ-Oxo-bridged diiron(iii) complexes of tripodal 4N ligands as catalysts for alkane hydroxylation reaction using m-CPBA as an oxidant: substrate vs. self hydroxylation.

1. Sc³⁺-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O₂ to Generate a Complex with an Fe^IV₂(μ-O)₂ Core.

2. Generation of a μ-1,2-hydroperoxo Fe^IIIFe^III and a μ-1,2-peroxo Fe^IVFe^III Complex.