Literature DB >> 28721736

Ru-Catalyzed Meta-C-H Benzylation of Arenes with Toluene Derivatives.

Bo Li1, Sheng-Long Fang1, Dan-Ying Huang2, Bing-Feng Shi1.   

Abstract

The Ru-catalyzed meta-C-H benzylation of arenes bearing pyridyl, pyrimidyl, and pyrazolyl directing groups with toluene derivatives has been reported. Heptafluoroisopropyl iodide (iC3F7I) was employed as both a mild oxidant and radical initiator. This reaction showed excellent site-selectivity and tolerated a wide range of functional groups, providing a new strategy for the synthesis of various diarylmethane moieties.

Entities:  

Year:  2017        PMID： 28721736     DOI： 10.1021/acs.orglett.7b01529

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Photo-Induced Ruthenium-Catalyzed C-H Benzylations and Allylations at Room Temperature.

Authors:  Julia Struwe; Korkit Korvorapun; Agnese Zangarelli; Lutz Ackermann
Journal:  Chemistry       Date:  2021-10-05       Impact factor: 5.020

2.  Pd(ii)-catalyzed meta-C-H bromination and chlorination of aniline and benzoic acid derivatives.

Authors:  Hao Wang; Lei Fu; Chunlin Zhou; Gang Li
Journal:  Chem Sci       Date:  2022-07-05       Impact factor: 9.969

3.  Photo-Induced Ruthenium-Catalyzed Double Remote C(sp2 )-H / C(sp3 )-H Functionalizations by Radical Relay.

Authors:  Yulei Wang; Shan Chen; Xinran Chen; Agnese Zangarelli; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-10       Impact factor: 16.823

4.  C7-Indole Amidations and Alkenylations by Ruthenium(II) Catalysis.

Authors:  Isaac Choi; Antonis M Messinis; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-29       Impact factor: 15.336

5.  Regiodivergent C-H and Decarboxylative C-C Alkylation by Ruthenium Catalysis: ortho versus meta Position-Selectivity.

Authors:  Korkit Korvorapun; Marc Moselage; Julia Struwe; Torben Rogge; Antonis M Messinis; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-25       Impact factor: 16.823

6.  Recyclable Ruthenium Catalyst for Distal meta-C-H Activation.

Authors:  Isaac Choi; Valentin Müller; Yanhui Wang; Kai Xue; Rositha Kuniyil; Loren B Andreas; Volker Karius; Johan G Alauzun; Lutz Ackermann
Journal:  Chemistry       Date:  2020-10-22       Impact factor: 5.236
  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.