Literature DB >> 28715010

Formation of ionic co-crystals of amphoteric azoles directed by the ionic liquid co-former 1-ethyl-3-methylimidazolium acetate.

Hatem M Titi1, Steven P Kelley1, Max E Easton1, Stephen D Emerson2, Robin D Rogers3.   

Abstract

The ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate was utilized as a liquid-state crystallization agent to form ionic co-crystals using amphoteric azoles selected as model compounds for active pharmaceutical ingredients. Weakly acidic azoles crystallize the IL relatively quickly, while stronger acidic azoles undergo slower ion exchange with the IL to form salts.

Entities:  

Year:  2017        PMID： 28715010     DOI： 10.1039/c7cc04429a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Exploring the role of ionic liquids to tune the polymorphic outcome of organic compounds.

Authors:  Qingying Zeng; Arijit Mukherjee; Peter Müller; Robin D Rogers; Allan S Myerson
Journal:  Chem Sci       Date:  2017-12-22       Impact factor: 9.825

2.  Three-Dimensional Supramolecular Architectures with MnII Ions Assembled from Hydrogen Bonding Interactions: Crystal Structures and Antiferromagnetic Properties.

Authors:  Yan-Li Gao; Yufei Wang; Liguo Gao; Jian Li; Yali Wang; Katsuya Inoue
Journal:  ACS Omega       Date:  2022-03-15
  2 in total

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