Literature DB >> 28704047

CuI-Catalyzed Fluorodesulfurization for the Synthesis of Monofluoromethyl Aryl Ethers.

Yang Geng1, Apeng Liang1, Xianying Gao1, Chengshan Niu2, Jingya Li2, Dapeng Zou1, Yusheng Wu2,3, Yangjie Wu1.   

Abstract

An efficient CuI-catalyzed fluorodesulfurization for the synthesis of monofluoromethyl aryl ethers using DAST at room temperature has been developed. This approach exhibits a good functional group tolerance, a broad substrate scope, and a high synthesis efficiency.

Entities:  

Year:  2017        PMID: 28704047     DOI: 10.1021/acs.joc.7b01438

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Direct and Chemoselective Electrophilic Monofluoromethylation of Heteroatoms (O-, S-, N-, P-, Se-) with Fluoroiodomethane.

Authors:  Raffaele Senatore; Monika Malik; Markus Spreitzer; Wolfgang Holzer; Vittorio Pace
Journal:  Org Lett       Date:  2020-01-31       Impact factor: 6.005

  1 in total

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