Literature DB >> 28696451

An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature.

Narsimhulu Pittala1, Franck Thétiot, Catherine Charles, Smail Triki, Kamel Boukheddaden, Guillaume Chastanet, Mathieu Marchivie.   

Abstract

We report a triazole-based trinuclear complex as the first example that displays a complete one-step first-order [HS-HS-HS] ↔ [LS-LS-LS] spin transition at 318 K. The strong ferro-elastic interactions, between the three metal centers, have been identified as the source of the concerted spin transition in this trinuclear complex.

Entities:  

Year:  2017        PMID： 28696451     DOI： 10.1039/c7cc04112h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Crystal structure of tetra-kis-(μ-4-benzyl-4H-1,2,4-triazole-κ2 N 1:N 2)tetra-fluoridodi-μ2-oxido-dioxidodisilver(I)divanadium(V).

Authors:  Ganna A Senchyk; Andrey B Lysenko; Eduard B Rusanov; Kostiantyn V Domasevitch
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2022-03-15

2.  Tunable microwave absorption of switchable complexes operating near room temperature.

Authors:  Olesia I Kucheriv; Viktor V Oliynyk; Volodymyr V Zagorodnii; Vilen L Launets; Olena V Penkivska; Igor O Fritsky; Il'ya A Gural'skiy
Journal:  RSC Adv       Date:  2020-06-05       Impact factor: 4.036
  2 in total

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