| Literature DB >> 28696437 |
Muniyandi Sankaralingam1, Yong-Min Lee, Xiaoyan Lu, Anil Kumar Vardhaman, Wonwoo Nam, Shunichi Fukuzumi.
Abstract
An iron(v)-oxo complex with a tetraamido macrocyclic ligand, [(TAML)FeV(O)]-, was produced by reacting [(TAML)FeIII]- with dioxygen without any electron source in acetone at 298 K. The autocatalytic mechanism of dioxygen activation for the formation of an iron(v)-oxo complex has been clarified based on the autocatalysis by radical chain initiators.Entities:
Year: 2017 PMID： 28696437 DOI： 10.1039/c7cc03742b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222