Literature DB >> 28678486

The Suzuki-Miyaura Coupling of Nitroarenes.

M Ramu Yadav1, Masahiro Nagaoka1, Myuto Kashihara1, Rong-Lin Zhong2, Takanori Miyazaki3, Shigeyoshi Sakaki2, Yoshiaki Nakao1.   

Abstract

Synthesis of biaryls via the Suzuki-Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl-nitro (Ar-NO2) bond by palladium, which represents an unprecedented elemental reaction.

Entities:  

Year:  2017        PMID： 28678486     DOI： 10.1021/jacs.7b03159

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  14 in total

1.  Suzuki-Miyaura Coupling of Simple Ketones via Activation of Unstrained Carbon-Carbon Bonds.

Authors:  Ying Xia; Jianchun Wang; Guangbin Dong
Journal:  J Am Chem Soc       Date:  2018-04-17       Impact factor: 15.419

2.  Activation of C-O and C-N Bonds Using Non-Precious-Metal Catalysis.

Authors:  Timothy B Boit; Ana S Bulger; Jacob E Dander; Neil K Garg
Journal:  ACS Catal       Date:  2020-09-10       Impact factor: 13.084

3.  Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future.

Authors:  Louis-Charles Campeau; Nilay Hazari
Journal:  Organometallics       Date:  2018-11-27       Impact factor: 3.876

4.  Heteroaryl-Heteroaryl, Suzuki-Miyaura, Anhydrous Cross-Coupling Reactions Enabled by Trimethyl Borate.

Authors:  Vincent M Kassel; Christopher M Hanneman; Connor P Delaney; Scott E Denmark
Journal:  J Am Chem Soc       Date:  2021-08-20       Impact factor: 16.383

5.  Rapidly Activating Pd-Precatalyst for Suzuki-Miyaura and Buchwald-Hartwig Couplings of Aryl Esters.

Authors:  Amira H Dardir; Patrick R Melvin; Ryan M Davis; Nilay Hazari; Megan Mohadjer Beromi
Journal:  J Org Chem       Date:  2017-12-12       Impact factor: 4.354

Review 6.  Recent Progress in Nitro-Promoted Direct Functionalization of Pyridones and Quinolones.

Authors:  Feiyue Hao; Nagatoshi Nishiwaki
Journal:  Molecules       Date:  2020-02-05       Impact factor: 4.411

7.  Suzuki-Miyaura Cross-Coupling of Esters by Selective O-C(O) Cleavage Mediated by Air- and Moisture-Stable [Pd(NHC)(μ-Cl)Cl]2 Precatalysts: Catalyst Evaluation and Mechanism.

Authors:  Shiyi Yang; Tongliang Zhou; Albert Poater; Luigi Cavallo; Steven P Nolan; Michal Szostak
Journal:  Catal Sci Technol       Date:  2021-03-25       Impact factor: 6.119

8.  A methylation platform of unconventional inert aryl electrophiles: trimethylboroxine as a universal methylating reagent.

Authors:  Boya Feng; Yudong Yang; Jingsong You
Journal:  Chem Sci       Date:  2020-05-25       Impact factor: 9.825

9.  Synthesis of thioethers, arenes and arylated benzoxazoles by transformation of the C(aryl)-C bond of aryl alcohols.

Authors:  Mingyang Liu; Zhanrong Zhang; Bingfeng Chen; Qinglei Meng; Pei Zhang; Jinliang Song; Buxing Han
Journal:  Chem Sci       Date:  2020-04-15       Impact factor: 9.825

10.  Tandem aza-Heck Suzuki and carbonylation reactions of O-phenyl hydroxamic ethers: complex lactams via carboamination.

Authors:  Run-Duo Gao; Scott A Shuler; Donald A Watson
Journal:  Chem Sci       Date:  2021-05-27       Impact factor: 9.825
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