| Literature DB >> 28670689 |
Tomohiro Sugahara1, Takahiro Sasamori2, Norihiro Tokitoh1.
Abstract
A 1,3-digerma-2-silacyclopenta-1,2-diene, that is, a 1,3-digerma-2-silaallene incorporated into a five-membered ring system, was synthesized and obtained as a stable orange solid. Owing to incorporation into a cyclic framework, the 1,3-digerma-2-silaallene moiety is highly bent, exhibiting a Si0 character for the central silicon moiety.Entities:
Keywords: digermacyclobutene; digermasilaallene; germanium; silicon; silylone
Year: 2017 PMID： 28670689 DOI： 10.1002/anie.201706297
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336