Literature DB >> 28653067

Thermal decomposition pathways of nitro-functionalized metal-organic frameworks.

Kyle A McDonald1, Nakeun Ko, Kyungkyou Noh, Jonathan C Bennion, Jaheon Kim, Adam J Matzger.   

Abstract

The decomposition behavior of high energy metal-organic frameworks (MOFs) with extensive nitration is disclosed. In contrast to the detonation behavior observed in molecular energetic compounds, deflagration transforms cubic MOFs into anisotropic carbon structures with highly dispersed metal. Both the structural metal and intimate mixing are found to be critical.

Entities:  

Year:  2017        PMID: 28653067     DOI: 10.1039/c7cc03354k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Do the fragments from decomposed ZIF-8 greatly affect some of the intramolecular proton-transfer of thymine? A quantum chemical study.

Authors:  Dejie Li; Ying Han; Huijuan Li; Ping Zhang; Qi Kang; Dazhong Shen
Journal:  RSC Adv       Date:  2018-07-31       Impact factor: 4.036

  1 in total

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