Literature DB >> 28640629

Divergent Coupling of β,γ-Unsaturated α-Ketoesters with Simple Olefins: Vinylation and [2 + 2] Cycloaddition.

Le Wang1,2, Jian Lv1,2,3, Sujia Li1,2, Sanzhong Luo1,2,3.   

Abstract

Catalytic direct conjugate addition and [2 + 2] cycloaddition reactions of β,γ-unsaturated α-ketoesters with simple olefins have been developed, affording vinylation products and functionalized cyclobutanes, respectively, in good yields with high regioselectivity.

Entities:  

Year:  2017        PMID: 28640629     DOI: 10.1021/acs.orglett.7b01291

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

Review 1.  Recent Visible Light and Metal Free Strategies in [2+2] and [4+2] Photocycloadditions.

Authors:  Marina Sicignano; Ricardo I Rodríguez; José Alemán
Journal:  European J Org Chem       Date:  2021-06-10
  1 in total

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