Literature DB >> 28636873

Mimicking natural phytohormones. 26-Hydroxycholestan-22-one derivatives as plant growth promoters.

Reyna Zeferino-Diaz1, J Ciciolil Hilario-Martinez1, Maricela Rodriguez-Acosta2, Alan Carrasco-Carballo3, Maria Guadalupe Hernandez-Linares4, Jesus Sandoval-Ramirez5, Maria A Fernandez-Herrera6.   

Abstract

26-Hydroxycholestan-22-one derivatives with oxygenated functions in the rings A and/or B were successfully synthesized from diosgenin. After the modifications of rings A and B, the spiroketal side chain was selectively opened through a Lewis acid mediated acetolysis to afford the cholestane derivatives. These compounds incorporate pharmacophores, which mimic the activity of natural phytohormones and show high growth promoting activity in Mexican rice cultivars using the rice lamina inclination test.
Copyright © 2017 Elsevier Inc. All rights reserved.

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Keywords:  26-Hydroxycholestan-22-one derivatives; Mimic phytohormones; Plant growth promoting activity; Rice lamina inclination test

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Year:  2017        PMID: 28636873     DOI: 10.1016/j.steroids.2017.06.004

Source DB:  PubMed          Journal:  Steroids        ISSN: 0039-128X            Impact factor:   2.668


  1 in total

1.  trans-Hydroboration-oxidation products in Δ5-steroids via a hydroboration-retro-hydroboration mechanism.

Authors:  J Ciciolil Hilario-Martínez; Fernando Murillo; Jair García-Méndez; Eugenia Dzib; Jesús Sandoval-Ramírez; Miguel Ángel Muñoz-Hernández; Sylvain Bernès; László Kürti; Fernanda Duarte; Gabriel Merino; María A Fernández-Herrera
Journal:  Chem Sci       Date:  2020-09-14       Impact factor: 9.825

  1 in total

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