| Literature DB >> 28635038 |
Clément Ghiazza1, Thierry Billard1,2, Anis Tlili1.
Abstract
The successful perfluoroalkylselenolation of alkynyl copper(I) compounds is described herein. The reaction occurs under oxidant free conditions at room temperature. This convenient one-pot procedure is based on the in situ generation of trifluoromethylselenyl chlorides. The developed system shows high functional group tolerance and also promotes the employment of fluoroalkyl derivatives.Entities:
Keywords: alkynes; copper; fluorine; selenium; trifluoromethylselenolation
Year: 2017 PMID： 28635038 DOI： 10.1002/chem.201702028
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236