Literature DB >> 28621939

[2]Rotaxane Formation by Transition State Stabilization.

Guillaume De Bo1, Guillaume Dolphijn1, Charlie T McTernan1, David A Leigh1.   

Abstract

We report on the synthesis of [2]rotaxanes driven by stabilization of the axle-forming transition state. A bifunctional macrocycle, with hydrogen bond donors at one end and acceptors at the other, is used to stabilize the charges that develop during the addition of a primary amine to a cyclic sulfate.

Entities:  

Year:  2017        PMID： 28621939     DOI： 10.1021/jacs.7b05640

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

1.  Docking rings in a solid: reversible assembling of pseudorotaxanes inside a zirconium metal-organic framework.

Authors:  Xia Li; Jialin Xie; Zhenglin Du; Long Jiang; Guangqin Li; Sanliang Ling; Kelong Zhu
Journal:  Chem Sci       Date:  2022-05-02       Impact factor: 9.969

2.  Selective access to constitutionally identical, orientationally isomeric calix[6]arene-based [3]rotaxanes by an active template approach.

Authors:  Margherita Bazzoni; Leonardo Andreoni; Serena Silvi; Alberto Credi; Gianpiero Cera; Andrea Secchi; Arturo Arduini
Journal:  Chem Sci       Date:  2021-04-01       Impact factor: 9.825

3.  Single-Step Enantioselective Synthesis of Mechanically Planar Chiral [2]Rotaxanes Using a Chiral Leaving Group Strategy.

Authors:  Chong Tian; Stephen D P Fielden; Borja Pérez-Saavedra; Iñigo J Vitorica-Yrezabal; David A Leigh
Journal:  J Am Chem Soc       Date:  2020-05-13       Impact factor: 15.419

4.  Weak functional group interactions revealed through metal-free active template rotaxane synthesis.

Authors:  Chong Tian; Stephen D P Fielden; George F S Whitehead; Iñigo J Vitorica-Yrezabal; David A Leigh
Journal:  Nat Commun       Date:  2020-02-06       Impact factor: 14.919

5.  Construction of pillar[4]arene[1]quinone-1,10-dibromodecane pseudorotaxanes in solution and in the solid state.

Authors:  Xinru Sheng; Errui Li; Feihe Huang
Journal:  Beilstein J Org Chem       Date:  2020-12-02       Impact factor: 2.883

6.  Influence of exo-Adamantyl Groups and endo-OH Functions on the Threading of Calix[6]arene Macrocycle.

Authors:  Veronica Iuliano; Carmen Talotta; Carmine Gaeta; Neal Hickey; Silvano Geremia; Ivan Vatsouro; Vladimir Kovalev; Placido Neri
Journal:  J Org Chem       Date:  2020-09-21       Impact factor: 4.354

7.  Self-Assembly of Stimuli-Responsive [2]Rotaxanes by Amidinium Exchange.

Authors:  Oleg Borodin; Yevhenii Shchukin; Craig C Robertson; Stefan Richter; Max von Delius
Journal:  J Am Chem Soc       Date:  2021-09-24       Impact factor: 15.419

8.  Diastereoselective synthesis of [1]rotaxanes via an active metal template strategy.

Authors:  Noël Pairault; Adrien Bessaguet; Romain Barat; Lucas Frédéric; Grégory Pieters; Jeanne Crassous; Isabelle Opalinski; Sébastien Papot
Journal:  Chem Sci       Date:  2020-12-29       Impact factor: 9.825

9.  Synthesis of diamido-bridged bis-pillar[5]arenes and tris-pillar[5]arenes for construction of unique [1]rotaxanes and bis-[1]rotaxanes.

Authors:  Ying Han; Li-Ming Xu; Cui-Yun Nie; Shuo Jiang; Jing Sun; Chao-Guo Yan
Journal:  Beilstein J Org Chem       Date:  2018-07-04       Impact factor: 2.883

10.  Active template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters.

Authors:  Javier Echavarren; Malcolm A Y Gall; Adrian Haertsch; David A Leigh; Vanesa Marcos; Daniel J Tetlow
Journal:  Chem Sci       Date:  2019-06-19       Impact factor: 9.825
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