Novel Slightly Reduced Graphene Oxide Based Proton Exchange Membrane with Constructed Long-Range Ionic Nanochannels via Self-Assembling of Nafion.

A facile method to prepare high-performance Nafion slightly reduced graphene oxide membranes (N-srGOMs) via vacuum filtration is proposed. The long-range connected ionic nanochannels in the membrane are constructed via the concentration-dependent self-assembling of the amphiphilic Nafion and the hydrophilic-hydrophobic interaction between graphene oxide (GO) and Nafion in water. The obtained N-srGOM possesses high proton conductivity, and low methanol permeability benefitted from the constructed unique interior structures. The proton conductivity of N-srGOM reaches as high as 0.58 S cm-1 at 80 °C and 95%RH, which is near 4-fold of the commercialized Nafion 117 membrane under the same condition. The methanol permeability of N-srGOM is 2.0 × 10-9 cm2 s-1, two-magnitude lower than that of Nafion 117. This novel membrane fabrication strategy has proved to be highly efficient in overcoming the "trade-off" effect between proton conductivity and methanol resistance and displays great potential in DMFC application.