| Literature DB >> 28608679 |
Terry Chu1, Sergei F Vyboishchikov2, Bulat M Gabidullin3, Georgii I Nikonov1.
Abstract
Reaction of the cyclic guanidine TolN═SIMe with the aluminum(I) compound NacNacAl (1) results in the unprecedented cleavage of the C-N multiple bond to give, after rearrangement, the carbene-ligated Al(III) amide, NacNac'Al(NHTol)(SIMe) (6). DFT calculations revealed that these reactions proceed via a bimolecular mechanism in which either the basic Al(I) center or the transient Al═NTol species deprotonates the methyl group of the NacNac ligand.Entities:
Year: 2017 PMID： 28608679 DOI： 10.1021/jacs.7b04841
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419